Vague recipeSource: Main
Route 1: Unknown
rendered page 8 / article p.8 · Methods - Materials
Work-upWashed with deionized H2O and Me2CO, respectively.
ActivationDried in air.
Synthesis evidence
Conductive 2D metal-organic framework for high-performance cathodes in aqueous rechargeable zinc batteries
Nam K.W., Park S.S., dos Reis R. et al. · Nature Communications · 2019 · 4948
4 structured synthesis routes
Completeness describes how fully the route could be reconstructed from the main article and supporting information.
Partial recipeSource: Main
Route 2: Drop Cast
rendered page 8 / article p.8 · Methods - Electrochemical tests
Solvents1-methyl-2-pyrrolidinone (NMP)
Additivesacetylene black; poly(vinylidene difluoride) (PVDF)
Atmospherevacuum oven for drying
Temperature70
Substrate orientationstainless steel (SUS 304) foil
Work-upSlurry cast onto stainless steel foil.
ActivationDried at 70 deg C in a vacuum oven.
Scalability contextActive material loading reported as 2 mg cm^-2.
Show 4 structured reagent records
| Role | Reagent | Amount / concentration | Source |
|---|---|---|---|
| Other | Cu3(HHTP)2 | 60 wt% | rendered page 8 / article p.8 · Methods - Electrochemical tests |
| Additive | acetylene black | 20 wt% | rendered page 8 / article p.8 · Methods - Electrochemical tests |
| Additive | poly(vinylidene difluoride) (PVDF) | 20 wt% | rendered page 8 / article p.8 · Methods - Electrochemical tests |
| Solvent | 1-methyl-2-pyrrolidinone (NMP) | Not specified | rendered page 8 / article p.8 · Methods - Electrochemical tests |
Partial recipeSource: Both
Route 3: Drop Cast
SI p.4 · Supplementary Fig. 5 caption · Supplementary Fig. 5
Solvents1-methyl-2-pyrrolidinone (NMP)
Additivesacetylene black; PVDF
Atmospherevacuum oven for drying
Temperature70
Substrate orientationstainless steel (SUS 304) foil
Work-upSlurry cast onto stainless steel foil.
ActivationDried at 70 deg C in a vacuum oven.
Scalability contextUsed to test higher active-material fraction; exact mass loading not separately stated.
Show 4 structured reagent records
| Role | Reagent | Amount / concentration | Source |
|---|---|---|---|
| Other | Cu3(HHTP)2 | 90 wt% | SI p.4 · Supplementary Fig. 5 caption · Supplementary Fig. 5 |
| Additive | acetylene black | 5 wt% | SI p.4 · Supplementary Fig. 5 caption · Supplementary Fig. 5 |
| Additive | PVDF | 5 wt% | SI p.4 · Supplementary Fig. 5 caption · Supplementary Fig. 5 |
| Solvent | 1-methyl-2-pyrrolidinone (NMP) | Not specified | SI p.4 · Supplementary Fig. 5 caption · Supplementary Fig. 5 |
Partial recipeSource: Main
Route 4: Other
rendered page 8 / article p.8 · Methods - Electrochemical tests
Metal precursorsZn film anode
Solventsdeionized H2O or acetonitrile (MeCN) electrolyte solvent
Additiveszinc trifluoromethanesulfonate electrolyte
Temperature25
Time1 h ageing before electrochemical processes
Work-upCoin cells assembled in two-electrode configuration and aged 1 h.
Show 3 structured reagent records
| Role | Reagent | Amount / concentration | Source |
|---|---|---|---|
| Electrolyte | Zn(CF3SO3)2 in deionized H2O | 3 M | rendered page 8 / article p.8 · Methods - Electrochemical tests |
| Electrolyte | Zn(CF3SO3)2 in acetonitrile (MeCN) | 0.25 M | rendered page 8 / article p.8 · Methods - Electrochemical tests |
| Other | Zn-film anode | 100 um thickness | rendered page 8 / article p.8 · Methods - Electrochemical tests |