Ambrogi E.K., Li Y., Chandra P. et al. · ACS Sensors · 2025 · 553-562
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
Optimised Ni3(HHTP)2-based electrodes detected NO at nanomolar concentrations in PBS using both GCE and screen-printed architectures.
Caveat: Detection in simulated wound fluid showed micromolar LODs because of decreased sensitivity/biofouling.
559-560 · Nitric Oxide Sensing with Screen-Printed Electrodes; Conclusions · Figures 5-6; Table S6 · Linked to 3 structured results
Pristine Ni3(HHTP)2 and Cu3(HHTP)2 electrodes showed the strongest voltammetric NO signal enhancements among the four HHTP MOFs.
Caveat: Co3(HHTP)2 had intrinsic redox activity near the NO window; pristine films had limited cycling stability.
556 · Comparison of Nitric Oxide Detection Performance · Figure 2 · Linked to 4 structured results
Simulated wound fluid reduced the sensitivity of Ni3(HHTP)2@SPE electrodes and indicated a need for further anti-biofouling development.
Caveat: Only simulated wound fluid was tested; no in vivo or real wound sample data were reported.
559-560 · Nitric Oxide Sensing with Screen-Printed Electrodes; Conclusions · Figures S39-S42; Table S6 · Linked to 3 structured results
A PEDOT:PSS adhesive layer stabilised Ni3(HHTP)2 films on smooth glassy carbon while retaining moderate NO signal enhancement.
Caveat: The adhesive layer reduced peak current relative to pristine Ni3(HHTP)2 but greatly reduced signal decay.
557-558 · Stabilization of MOF Films with Polymers · Figure 4 · Linked to 4 structured results
The metal centre identity, not simply surface area or layer stacking, is the primary driver of NO sensitivity in the HHTP MOF series.
Caveat: No direct NO binding measurement was reported; mechanism inferred from electrochemical trends and literature.
556 and 560 · Results and Discussion; Conclusions · Figure 2; Table S1 · Linked to 6 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| Co3(HHTP)2Browse family: Co₃(HHTP)₂ / Co–HHTP | Co3(HHTP)2Co2+ · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP) | 2D · PristineLayered conductive HHTP MOF; ABAB stacking with intercalated layers. | 554-555 · Characterization of HHTP MOFs · Figure 1 |
| Bare carbon control electrodes | Not specified | unknown · Model SystemGlassy carbon and carbon-paste screen-printed electrodes used as non-MOF controls. | 557-559 · Amperometric Detection; Nitric Oxide Sensing with Screen-Printed Electrodes · Figures 5-6 |
| Cu3(HHTP)2Browse family: Cu₃(HHTP)₂ / Cu–HHTP | Cu3(HHTP)2Cu2+ · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP) | 2D · PristineLayered conductive HHTP MOF; AAAA/slipped-parallel stacking without intercalated layer. | 555 · Characterization of HHTP MOFs · Figure 1 |
| Ni3(HHTP)2Browse family: Ni₃(HHTP)₂ / Ni–HHTP | Ni3(HHTP)2Ni2+ · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP) | 2D · PristineLayered conductive HHTP MOF; ABAB stacking with intercalated layers. | 554-555 · Characterization of HHTP MOFs · Figure 1 |
| Zn3(HHTP)2Browse family: Zn–HHTP family | Zn3(HHTP)2Zn2+ · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP) | 2D · PristineLayered HHTP MOF; diffraction resembles slipped-parallel/AAAA-type Cu3(HHTP)2 packing. | 555 · Characterization of HHTP MOFs · Figure 1 |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| Bare glassy carbon electroderesearch_0194__mat__control_electrodes | Electrode · Model System · Model | Polished, unmodified control electrode.3 mm diameter glassy carbon electrode | 557-558 · Amperometric Detection of Nitric Oxide · Figure 5 |
| Bare screen-printed electroderesearch_0194__mat__control_electrodes | Electrode · Model System · Model | Unmodified printed working electrode used as WE2 control.Carbon-paste screen-printed electrode on PET | 558-559 · Nitric Oxide Sensing with Ni3(HHTP)2-Functionalized Screen-Printed Electrodes · Figure 6 |
| Co3(HHTP)2 dropcast on glassy carbon electroderesearch_0194__mat__co_hhtp | Electrode · Target Sample · Pristine Framework | Dropcast thin-film working electrode.3 mm diameter glassy carbon electrode · two 2.5 uL drops of MOF suspension | 555 · General Preparation of HHTP MOF Electrodes |
| Co3(HHTP)2 microcrystalline powderresearch_0194__mat__co_hhtp | Powder · Pristine Control · Pristine Framework | Hydrothermally prepared, activated powder. | S3 · Synthesis Of Triphenylene-Based Metal-Organic Frameworks · Figure S1 |
| Cu3(HHTP)2 dropcast on glassy carbon electroderesearch_0194__mat__cu_hhtp | Electrode · Target Sample · Pristine Framework | Dropcast thin-film working electrode.3 mm diameter glassy carbon electrode · two 2.5 uL drops of MOF suspension | 555 · General Preparation of HHTP MOF Electrodes |
| Cu3(HHTP)2 microcrystalline powderresearch_0194__mat__cu_hhtp | Powder · Pristine Control · Pristine Framework | Hydrothermally prepared, activated powder. | S4 · Synthesis Of Triphenylene-Based Metal-Organic Frameworks · Figure S1 |
| Ni3(HHTP)2 dropcast on glassy carbon electroderesearch_0194__mat__ni_hhtp | Electrode · Target Sample · Pristine Framework | Dropcast thin-film working electrode.3 mm diameter glassy carbon electrode · two 2.5 uL drops of MOF suspension | 555 · General Preparation of HHTP MOF Electrodes |
| Nafion@Ni3(HHTP)2@GCEresearch_0194__mat__ni_hhtp | Electrode · Composite Sample · Composite | Polymer coating on top of MOF film.3 mm diameter glassy carbon electrode · 5 uL Nafion solution coated on Ni3(HHTP)2 film | S7 · Polymer Coatings · Figure S26 |
| Ni3(HHTP)2@PEDOT:PSS@GCEresearch_0194__mat__ni_hhtp | Electrode · Composite Sample · Composite | MOF film deposited on conductive polymer adhesive layer.PEDOT:PSS adhesive layer on glassy carbon electrode · 2.5 uL 0.3-0.4% PEDOT:PSS adhesive layer plus two 2.5 uL MOF suspension drops | S7-S8 · Preparation of HHTP MOF Electrodes |
| Ni3(HHTP)2 + PEDOT:PSS@GCEresearch_0194__mat__ni_hhtp | Electrode · Composite Sample · Composite | PEDOT:PSS mixed into MOF suspension as a binder.3 mm diameter glassy carbon electrode · two 2-2.5 uL drops of Ni3(HHTP)2/PEDOT:PSS suspension | S7 · Polymer Binders · Table S2 |
| Ni3(HHTP)2 microcrystalline powderresearch_0194__mat__ni_hhtp | Powder · Target Sample · Pristine Framework | Hydrothermally prepared, activated powder. | S3 · Synthesis Of Triphenylene-Based Metal-Organic Frameworks · Figure S1 |
| PPD@Ni3(HHTP)2@GCEresearch_0194__mat__ni_hhtp | Electrode · Composite Sample · Composite | Poly(o-phenylenediamine) coating tested with Ni3(HHTP)2.3 mm diameter glassy carbon electrode · electropolymerised PPD coating | S7 · Polymer Coatings · Figure S24 |
| Ni3(HHTP)2@SPEresearch_0194__mat__ni_hhtp | Electrode · Composite Sample · Composite | Ni3(HHTP)2-functionalised working electrode in miniaturised SPE device.Carbon-paste screen-printed electrode on PET · two 0.5 uL drops on WE1 | S8 · Preparation of Ni3(HHTP)2-functionalized screen-printed electrodes · Figures S35-S37 |
| Zn3(HHTP)2 dropcast on glassy carbon electroderesearch_0194__mat__zn_hhtp | Electrode · Target Sample · Pristine Framework | Dropcast thin-film working electrode.3 mm diameter glassy carbon electrode · two 2.5 uL drops of MOF suspension | 555 · General Preparation of HHTP MOF Electrodes |
| Zn3(HHTP)2 microcrystalline powderresearch_0194__mat__zn_hhtp | Powder · Pristine Control · Pristine Framework | Hydrothermally prepared, activated powder. | 555 · Experimental Methods |