Electrochemistry Application — Truxone-Based Conductive Metal-Organic Frameworks for the Oxygen Reductive Reaction

3 measurement groups · 6 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

truxone-Cu MOF-modified GC electrode · Electrode

Scan rate 50 mV s-1; potentials referenced to RHE; conventional three-electrode system.

Temperature: room temperature
Atmosphere: O2 or N2 saturated electrolyte
Geometry: MOF-modified GC electrode
Context: MOF/Nafion/GC electrode composite
Measurement source: p006 / article p.12695 · Results and Discussion · Figure 5a

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
truxene-Cu MOF basic-electrolyte stability control	could not exist stably on the electrode in the basic environment	—	—	Qualitative Qualitative	p006 / article p.12695 · Results and Discussion

truxone-Cu MOF-modified GC electrode · Electrode

K-L from 0.4, 0.45 and 0.5 V polarization curves; Tafel at 1500 rpm; stability at 0.65 V for 10000 s in O2-saturated 0.1 M KOH.

Temperature: room temperature
Atmosphere: O2 saturated electrolyte
Geometry: MOF-modified GC/RDE; graphite counter electrode for steady-state potentiostatic measurement
Context: MOF/Nafion/GC electrode composite
Measurement source: p006-p007 / article pp.12695-12696 · Results and Discussion · Figure 5d; Figures S33-S34

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Koutecky-Levich ORR electron-transfer number	about 3.6	—	about	Text Approximate	p006 / article p.12695 · Results and Discussion · Figure 5d
chronoamperometric current retention after 10000 s	80.5% of initial current density remained after 10000 s at 0.65 V	—	—	Text Exact Reported	p006-p007 / article pp.12695-12696 · Results and Discussion · Figure S34
ORR Tafel slope	114 mV dec-1	—	—	Text Exact Reported	p006 / article p.12695 · Results and Discussion · Figure S33

truxone-Cu MOF-modified GC electrode · Electrode

pH = 13; RDE at 1500 rpm for onset comparison; scan rate 5 mV s-1; additional speeds 500-2500 rpm.

Temperature: room temperature
Atmosphere: O2 saturated 0.1 M KOH
Geometry: 5 mm GC RDE modified with MOF/Nafion ink
Context: MOF/Nafion/GC electrode composite
Measurement source: p006 / article p.12695 · Results and Discussion · Figure 5b,c

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
ORR reaction current density	-1.5 mA cm-2	—	—	Text Exact Reported	p006 / article p.12695 · Results and Discussion · Figure 5b
ORR onset potential at j = -50 uA cm-2	0.79 V vs RHE	—	—	Text Exact Reported	p006 / article p.12695 · Results and Discussion · Figure 5b