Other — Multiple-Hydrogen-Bond Approach to Uncommon Pd(III) Oxidation State: A Pd-Br Chain with High Conductivity and Thermal Stability

2 measurement groups · 2 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Copper-luster rod-like single crystals of compound 3 · Single Crystal

DSC thermograms at a scan rate of 10 K min-1, heating and cooling.

Temperature: approximately 325-470
Context: pristine target material
Measurement source: SI p.S5 · Differential scanning calorimetry (DSC) of 3 · Figure S2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
AV-MV phase-transition peak	no peak attributable to an AV-MV phase transition up to 443 K	—	—	Text Qualitative	main p.2, article p.6563 · Thermal stability of AV state · Figures S1 and S2

Copper-luster rod-like single crystals of compound 3 · Single Crystal

TGA/DTA trace at a scan rate of 10 K min-1.

Temperature: 300-650 approximately
Context: pristine target material
Measurement source: SI p.S5 · Thermogravimetric analysis (TGA) and differential thermal analysis (DTA) of 3 · Figure S1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
decomposition temperatureMarked as a best value within this paper	443 K	443 K	—	Text Exact Reported	main p.2, article p.6563 · Thermal stability of AV state · Figures S1 and S2