Measurement evidence
A Conductive Cu-Based Metal–Organic Framework Ribbon with High-Density Redox-Active Centers as Cathode for Stable High-Capacity Lithium-Ion Batteries · Yang M., Wang Y., Huang Y.-F. et al. · Angewandte Chemie - International Edition · 2025 · e202421008
Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.
DDA-Cu LIB cathode, low loading · Electrode
FTIR of pristine, lithiated and delithiated DDA-Cu cathode
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| FTIR reversible redox bands | N-H 3210-3432 cm^-1 disappears on Li insertion; C=O and C=N at 1610 and 1544 cm^-1 disappear after lithiation and reappear after delithiation | — | — | Text Rounded Reported | 8 · Results and Discussion · Figure S32 |
DDA-Cu LIB cathode, low loading · Electrode
Pristine, discharged to 1 V, and charged to 3.8 V DDA-Cu cathodes
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Cu 2p redox change | Cu2+ peaks at 934.6/954.5 eV reduce; Cu+ peaks at 932.8/952.4 eV appear after lithiation | — | — | Text Rounded Reported | 8 · Results and Discussion · Figure 4d |
| N 1s redox change | C=N peak decreases on lithiation and increases after delithiation; Cu-N peak nearly unchanged | — | — | Text Qualitative | 7 · Results and Discussion · Figure 4b |
| O 1s redox change | C=O at 532.8 eV weakens and C-O at 531.3 eV increases after lithiation | — | — | Text Qualitative | 7 · Results and Discussion · Figure 4c |
activated DDA-Cu MOF powder · Powder
Chemical bonding/coordination characterisation of pristine DDA-Cu
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| FTIR N-H region | 3210-3432 cm^-1 weak for DDA-Cu compared with DDA | — | — | Text Range | 3 · Results and Discussion · Figure S7 |
| C 1s peak assignments | 284.8, 286.1, 287.6, 289.1 eV for C=C/C-C, C-N, C-O and C=O | — | — | Text Rounded Reported | 3-4 · Results and Discussion · Figure S8 |
| Cu 2p peak assignments | 934.6 and 954.5 eV for Cu2+; satellites at 938.8, 944.3, 959 and 963.4 eV | — | — | Text Rounded Reported | 3-4 · Results and Discussion · Figure S8 |
| N 1s peak assignments | 398.7, 399.3, 400.1 eV for C=N, Cu-N and C-N | — | — | Text Rounded Reported | 3-4 · Results and Discussion · Figure S8 |
| O 1s peak assignments | 531.3 and 532.8 eV for C-O and C=O | — | — | Text Rounded Reported | 3-4 · Results and Discussion · Figure S8 |