cMOF Evidence Base

Synthesis evidence

A Conductive Cu-Based Metal–Organic Framework Ribbon with High-Density Redox-Active Centers as Cathode for Stable High-Capacity Lithium-Ion Batteries

Yang M., Wang Y., Huang Y.-F. et al. · Angewandte Chemie - International Edition · 2025 · e202421008

2 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Partial recipeSource: SI

Route 1: Other

S2 · Electrochemical Measurements

Metal precursorsDDA-Cu active material
Solventsslurry solvent not specified
AdditivesSuper-P; CMC/SBR binder mass ratio 1:1
Atmosphereargon glovebox for cell assembly; O2 and H2O below 0.1 ppm
Temperature70
Time12
Substrate orientationcarbon-coated aluminium foil
Work-upslurry cast on carbon-coated aluminium foil and dried under vacuum
Activationvacuum drying at 70 C for 12 h
Scalability contextElectrode composition reported, but slurry solvent and coating parameters are not specified.
Show 4 structured reagent records
RoleReagentAmount / concentrationSource
OtherDDA-Cu active material70 wt%S2 · Electrochemical Measurements
AdditiveSuper-P20 wt%S2 · Electrochemical Measurements
AdditiveCMC/SBR binder10 wt%; CMC/SBR mass ratio 1:1S2 · Electrochemical Measurements
ElectrolyteLiTFSI in DOL:DME4 M; v:v 1:1S2 · Electrochemical Measurements
Complete recipeSource: Both

Route 2: Other

S6 · Synthesis of DDA-Cu MOF

Metal precursorsCu(CH3COO)2.H2O, 22.2 mg in ethanol/water solution B
Linker precursorsDDA, 30 mg in ethanol/water solution A
Solventsethanol and water; solution A 100 mL ethanol + 100 mL water; solution B 100 mL ethanol + 100 mL water; THF Soxhlet wash
Additivesnone reported
Atmosphereair for reaction; final drying under vacuum
Temperature90
Time24
Oxidant / reductantnone reported
Work-upcentrifuged at 9500 rpm; washed/centrifuged with ethanol and water until clear supernatant; Soxhlet extracted with THF for 48 h
Activationdried in vacuum at 90 C for 12 h
Scalability contextBatch solution synthesis; SI gives milligram reagent quantities and 200 mL + 200 mL solvent volumes.
Show 5 structured reagent records
RoleReagentAmount / concentrationSource
LinkerDDA30 mgS6 · Synthesis of DDA-Cu MOF
Metal SourceCu(CH3COO)2.H2O22.2 mgS6 · Synthesis of DDA-Cu MOF
Solventethanol100 mL in solution A; 100 mL in solution BS6 · Synthesis of DDA-Cu MOF
Solventwater100 mL in solution A; 100 mL in solution BS6 · Synthesis of DDA-Cu MOF
SolventtetrahydrofuranSoxhlet wash, 48 hS6 · Synthesis of DDA-Cu MOF