Electrical Transport — Dominant Role of Hole Transport Pathway in Achieving Record High Photoconductivity in Two-Dimensional Metal–Organic Frameworks

4 measurement groups · 23 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Cu-HHTP tape-cell sample · Unknown

400 nm pump; pump power 90 mW; THz probe; tape-cell samples thick enough to absorb pump pulse; time delay spanning 125 ps.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
OPTP fit A1 (Cu)	-0.802	—	—	SI Table Exact Reported	p008 / SI p.S7 · S5 · Table S2
OPTP fit A2 (Cu)	-0.098	—	—	SI Table Exact Reported	p008 / SI p.S7 · S5 · Table S2
OPTP fit tau1 (Cu)	0.186	—	—	SI Table Exact Reported	p008 / SI p.S7 · S5 · Table S2
OPTP fit tau2 (Cu)	4.574	—	—	SI Table Exact Reported	p008 / SI p.S7 · S5 · Table S2
OPTP fit y0 (Cu)	-0.019	—	—	SI Table Exact Reported	p008 / SI p.S7 · S5 · Table S2
reported conductivity-vs-time maximum from calculationMarked as a best value within this paper	maximum of this trace is 65.5 S/m	—	—	Text Exact Reported	p004 / SI p.S3 · Photoconductivity calculations
photoconductivity maximumMarked as a best value within this paper	65.5 S/m	—	—	Text Exact Reported	p003-p004 · Results and Discussion · Table S3
sample-cell thickness used in photoconductivity calculation	3.5 um	—	—	Text Exact Reported	p004 / SI p.S3 · Photoconductivity calculations
photoconductive THz attenuationMarked as a best value within this paper	0.3 %	—	—	Text Exact Reported	p003 · Results and Discussion · Figure 3

Cu/Zn-HHTP tape-cell sample · Unknown

400 nm pump; same OPTP comparison and Table S2 exponential fit.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
effect of Zn substitution on THz signal	strongly diminishes this signal	—	—	Text Qualitative	p003 · Results and Discussion · Figure 3
OPTP fit A1 (Cu/Zn)	-0.526	—	—	SI Table Exact Reported	p008 / SI p.S7 · S5 · Table S2
OPTP fit A2 (Cu/Zn)	-0.022	—	—	SI Table Exact Reported	p008 / SI p.S7 · S5 · Table S2
OPTP fit tau1 (Cu/Zn)	0.074	—	—	SI Table Exact Reported	p008 / SI p.S7 · S5 · Table S2
OPTP fit tau2 (Cu/Zn)	2.717	—	—	SI Table Exact Reported	p008 / SI p.S7 · S5 · Table S2
OPTP fit y0 (Cu/Zn)	-0.004	—	—	SI Table Exact Reported	p008 / SI p.S7 · S5 · Table S2

Zn-HHTP tape-cell sample · Unknown

400 nm pump; same OPTP comparison and Table S2 exponential fit.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
OPTP fit A1 (Zn)	-0.346	—	—	SI Table Exact Reported	p008 / SI p.S7 · S5 · Table S2
OPTP fit A2 (Zn)	-0.002	—	—	SI Table Exact Reported	p008 / SI p.S7 · S5 · Table S2
OPTP fit tau1 (Zn)	0.055	—	—	SI Table Exact Reported	p008 / SI p.S7 · S5 · Table S2
OPTP fit tau2 (Zn)	1.12	—	—	SI Table Exact Reported	p008 / SI p.S7 · S5 · Table S2
OPTP fit y0 (Zn)	-0.01	—	—	SI Table Exact Reported	p008 / SI p.S7 · S5 · Table S2
Zn-HHTP THz attenuation	marginal THz attenuation	—	—	Text Qualitative	p005 · Results and Discussion · Figure 3

Cu-HHTP tape-cell sample · Unknown

Ground-state THz-TDS at 300, 200 and 100 K measured absorption coefficient, refractive index and permittivity.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
carrier freeze-out interpretation	free charges are frozen out and the material is semiconductive	—	—	Text Qualitative	p004 · Results and Discussion · Figure S5
temperature trend in THz-TDS response	absorption coefficient, refractive index and permittivity shift lower with decreasing temperature	—	—	Caption Qualitative	p008 / SI p.S7 · S5 · Figure S5