Synthesis · Dominant Role of Hole Transport Pathway in Achieving Record High Photoconductivity in Two-Dimensional Metal–Organic Frameworks

3 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Complete recipeSource: SI

Route 1: Solvothermal

p003 / SI p.S2 · S1. Synthesis of M-HHTP MOFs

Metal precursorsCu(Ac)2.H2O

Linker precursors2,3,6,7,10,11-Hexahydroxytriphenylene (HHTP), 65 mg, 0.2 mmol

Solvents1 mL NMP + 9 mL DI H2O for HHTP; metal source dissolved in 5 mL DI H2O

Additivesnone reported

Atmospherenot reported

Temperature60

Time12

Substrate orientationnot applicable

Oxidant / reductantno external oxidant/reductant reported; FTIR suggests ligands were partially oxidised during reaction

Work-upSequential washing with deionised water (3 times, 3 mL each) and acetone (6 times, 3 mL each); collected by centrifugation at 6000 rpm.

ActivationDried overnight in an oven at 50 deg C for further characterisation.

Scalability contextSmall-batch solution/oven synthesis; no scale-up discussion.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	Cu(Ac)2.H2O	60 mg, 0.3 mmol	p003 / SI p.S2 · S1. Synthesis of M-HHTP MOFs
Linker	2,3,6,7,10,11-Hexahydroxytriphenylene (HHTP)	65 mg, 0.2 mmol	p003 / SI p.S2 · S1. Synthesis of M-HHTP MOFs
Solvent	NMP	1 mL	p003 / SI p.S2 · S1. Synthesis of M-HHTP MOFs
Solvent	DI H2O	9 mL for HHTP solution plus 5 mL for metal-source solution	p003 / SI p.S2 · S1. Synthesis of M-HHTP MOFs

Complete recipeSource: SI

Route 2: Solvothermal

p003 / SI p.S2 · S1. Synthesis of M-HHTP MOFs

Metal precursorsCu(Ac)2.H2O; Zn(acac)2

Linker precursors2,3,6,7,10,11-Hexahydroxytriphenylene (HHTP), 65 mg, 0.2 mmol

Solvents1 mL NMP + 9 mL DI H2O for HHTP; metal source dissolved in 5 mL DI H2O

Additivesnone reported

Atmospherenot reported

Temperature60

Time12

Substrate orientationnot applicable

Oxidant / reductantno external oxidant/reductant reported; FTIR suggests ligands were partially oxidised during reaction

Work-upSequential washing with deionised water (3 times, 3 mL each) and acetone (6 times, 3 mL each); collected by centrifugation at 6000 rpm.

ActivationDried overnight in an oven at 50 deg C for further characterisation.

Scalability contextSmall-batch solution/oven synthesis; no scale-up discussion.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	Cu(Ac)2.H2O; Zn(acac)2	30 mg, 0.15 mmol; 39 mg, 0.15 mmol	p003 / SI p.S2 · S1. Synthesis of M-HHTP MOFs
Linker	2,3,6,7,10,11-Hexahydroxytriphenylene (HHTP)	65 mg, 0.2 mmol	p003 / SI p.S2 · S1. Synthesis of M-HHTP MOFs
Solvent	NMP	1 mL	p003 / SI p.S2 · S1. Synthesis of M-HHTP MOFs
Solvent	DI H2O	9 mL for HHTP solution plus 5 mL for metal-source solution	p003 / SI p.S2 · S1. Synthesis of M-HHTP MOFs

Complete recipeSource: SI

Route 3: Solvothermal

p003 / SI p.S2 · S1. Synthesis of M-HHTP MOFs

Metal precursorsZn(acac)2

Linker precursors2,3,6,7,10,11-Hexahydroxytriphenylene (HHTP), 65 mg, 0.2 mmol

Solvents1 mL NMP + 9 mL DI H2O for HHTP; metal source dissolved in 5 mL DI H2O

Additivesnone reported

Atmospherenot reported

Temperature60

Time12

Substrate orientationnot applicable

Oxidant / reductantno external oxidant/reductant reported; FTIR suggests ligands were partially oxidised during reaction

Work-upSequential washing with deionised water (3 times, 3 mL each) and acetone (6 times, 3 mL each); collected by centrifugation at 6000 rpm.

ActivationDried overnight in an oven at 50 deg C for further characterisation.

Scalability contextSmall-batch solution/oven synthesis; no scale-up discussion.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	Zn(acac)2	78 mg, 0.3 mmol	p003 / SI p.S2 · S1. Synthesis of M-HHTP MOFs
Linker	2,3,6,7,10,11-Hexahydroxytriphenylene (HHTP)	65 mg, 0.2 mmol	p003 / SI p.S2 · S1. Synthesis of M-HHTP MOFs
Solvent	NMP	1 mL	p003 / SI p.S2 · S1. Synthesis of M-HHTP MOFs
Solvent	DI H2O	9 mL for HHTP solution plus 5 mL for metal-source solution	p003 / SI p.S2 · S1. Synthesis of M-HHTP MOFs