Liu Y., Wang X., Wu Z.-S. et al. · Advanced Functional Materials · 2025 · 2505535
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
VO@Cu-HHTP-2 flexible pouch batteries retain high rate capability, low folded-state impedance, and near-quantitative cycling retention.
Caveat: Pouch-cell construction details are limited to component schematic and gel-electrolyte recipe; device dimensions and active mass are not reported.
p008 · 2.4. Soft-Pack Battery · Figure 6 · Linked to 5 structured results
An optimal amount of Cu-HHTP in VO@Cu-HHTP-2 gives higher capacity and rate capability than pristine VO and other Cu-HHTP loadings.
Caveat: Electrode data include Super-P and PVDF in all samples; capacity is normalised as reported by the authors.
p005 · 2.2. Electrochemical Performance Evaluation · Figure 3d-e · Linked to 4 structured results
Anchored Cu-HHTP suppresses vanadium dissolution from V3O7.H2O in Zn(CF3SO3)2 electrolyte.
Caveat: ICP values are after a stated soaking comparison; exact immersion duration is inferred from Figure S4 as 10 days in the text.
p004 · 2.2. Electrochemical Performance Evaluation · Figure S4 · Linked to 2 structured results
Anchored Cu-HHTP enhances electrical conductivity and charge-transfer kinetics of V3O7.H2O nanobelts through pi-d conjugation.
Caveat: No direct first-hand bulk electrical conductivity value for VO@Cu-HHTP is reported; support is indirect through EIS/GITT and performance.
p002 · Introduction · Linked to 3 structured results
VO@Cu-HHTP-2 stores charge through a dual H+ and Zn2+ co-insertion mechanism with reversible V3O7.H2O peak shifts and ZVO phase formation.
Caveat: Mechanism inferred from ex situ diffraction, XPS, and TEM rather than in situ chemical quantification.
p007 · 2.3. Mechanism Discussion · Figure 5 · Linked to 3 structured results
The VO@Cu-HHTP-2 redox reaction is mainly controlled by surface capacitance, supporting high-rate zinc storage.
Caveat: Only b2, b3, b5, and b6 are reported; no b1/b4 values are provided.
p005 · 2.2. Electrochemical Performance Evaluation · Figure 4b-c · Linked to 5 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| Cu-HHTP conductive metal-organic frameworkBrowse family: Cu₃(HHTP)₂ / Cu–HHTP | Cu-HHTP; commonly Cu3(HHTP)2 but exact stoichiometry not specified in this paperCu ions from anhydrous copper acetate · HHTP = hexahydroxytriphenylene | 2D · Pristine2D conductive MOF with prominent diffraction peaks at 5.0, 9.6, and 12.6 degrees assigned to the (100), (200), and (210) planes. | p002 · 2.1. Structural and Morphological Characterization · Figure 1a; Figure S1 |
| Polyacrylamide gel electrolyte | PAM gel containing 3 M Zn(CF3SO3)2 | unknown · UnknownPolymer gel electrolyte separator for flexible pouch batteries. | SI text · S1.1.3. Synthesis of polyacrylamide (PAM) gel electrolyte |
| V3O7.H2O vanadium oxide nanobelts | V3O7.H2OV-O polyhedral framework containing V5+/V4+ redox centres | unknown · PristineOrthorhombic V3O7.H2O phase, space group Pnam, with unit cell a = 16.8714 A, b = 9.3325 A, c = 3.6348 A. | p002 · 2.1. Structural and Morphological Characterization · Figure 1a |
| VO@Cu-HHTP compositeBrowse family: Cu₃(HHTP)₂ / Cu–HHTP | V3O7.H2O@Cu-HHTPV-O nanobelt host plus Cu nodes in anchored Cu-HHTP · HHTP in anchored Cu-HHTP | unknown · CompositeCu-HHTP anchored on V3O7.H2O nanobelts by pi-d conjugation; composite retains V3O7.H2O reflections with a Cu-HHTP peak near 8.4 degrees. | p002 · 2.1. Structural and Morphological Characterization · Figure 1a |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| Cu-HHTP composite cathode electroderesearch_0226__mat__m_cu_hhtp | Electrode · Pristine Control · Composite | Active material/Super-P/PVDF = 7:2:1 in NMP, scraped onto carbon paper and vacuum dried at 60 C.carbon paper · active material loading 2-3 mg cm-2 | SI text · S1.3 Electrochemical characterization |
| Cu-HHTPresearch_0226__mat__m_cu_hhtp | Powder · Pristine Control · Pristine Framework | Black powder obtained by hydrothermal reaction and washing. | SI text · S1.1.1. Synthesis of Cu-HHTP conductive MOFs |
| PAM gel electrolyte separatorresearch_0226__mat__m_pam_gel | Unknown · Composite Component · Guest Loaded | Acrylamide polymerised in 3 M Zn(CF3SO3)2 with persulfate initiator and bis(acrylamide) crosslinker.mould 100 mm x 70 mm x 2 mm | SI text · S1.1.3. Synthesis of polyacrylamide (PAM) gel electrolyte |
| VO@Cu-HHTP-1 composite cathode electroderesearch_0226__mat__m_vo_cu_hhtp | Electrode · Composite Sample · Composite | VO@Cu-HHTP-1 active material/Super-P/PVDF = 7:2:1 in NMP, scraped onto carbon paper and vacuum dried at 60 C.carbon paper · active material loading 2-3 mg cm-2 | SI text · S1.3 Electrochemical characterization |
| VO@Cu-HHTP-1research_0226__mat__m_vo_cu_hhtp | Nanosheet · Composite Sample · Composite | VO@Cu-HHTP composite prepared with 0.025 g Cu-HHTP added to V2O5/H2O2 precursor solution before hydrothermal treatment. | SI text · S1.1.2. Synthesis of V3O7.H2O and VO@Cu-HHTP |
| VO@Cu-HHTP-2 composite cathode electroderesearch_0226__mat__m_vo_cu_hhtp | Electrode · Target Sample · Composite | VO@Cu-HHTP-2 active material/Super-P/PVDF = 7:2:1 in NMP, scraped onto carbon paper and vacuum dried at 60 C.carbon paper · active material loading 2-3 mg cm-2 | SI text · S1.3 Electrochemical characterization |
| Zn||VO@Cu-HHTP-2 pouch batteryresearch_0226__mat__m_vo_cu_hhtp | Electrode · Target Sample · Composite | Flexible pouch device composed of VO@Cu-HHTP-2 cathode, PAM gel electrolyte separator, Zn foil anode, and aluminum-plastic encapsulation.aluminum-plastic film pouch | p008 · 2.4. Soft-Pack Battery · Figure 6a |
| VO@Cu-HHTP-2research_0226__mat__m_vo_cu_hhtp | Nanosheet · Target Sample · Composite | Optimum VO@Cu-HHTP composite prepared with 0.05 g Cu-HHTP and hydrothermal treatment at 200 C for 48 h. | p003 · 2.1. Structural and Morphological Characterization · Figure 2b |
| VO@Cu-HHTP-3 composite cathode electroderesearch_0226__mat__m_vo_cu_hhtp | Electrode · Composite Sample · Composite | VO@Cu-HHTP-3 active material/Super-P/PVDF = 7:2:1 in NMP, scraped onto carbon paper and vacuum dried at 60 C.carbon paper · active material loading 2-3 mg cm-2 | SI text · S1.3 Electrochemical characterization |
| VO@Cu-HHTP-3research_0226__mat__m_vo_cu_hhtp | Nanosheet · Composite Sample · Composite | VO@Cu-HHTP composite prepared with 0.075 g Cu-HHTP added to V2O5/H2O2 precursor solution before hydrothermal treatment. | SI text · S1.1.2. Synthesis of V3O7.H2O and VO@Cu-HHTP |
| VO composite cathode electroderesearch_0226__mat__m_vo | Electrode · Pristine Control · Composite | VO active material/Super-P/PVDF = 7:2:1 in NMP, scraped onto carbon paper and vacuum dried at 60 C.carbon paper · active material loading 2-3 mg cm-2 | SI text · S1.3 Electrochemical characterization |
| VO; pure V3O7.H2Oresearch_0226__mat__m_vo | Nanosheet · Pristine Control · Unknown | Hydrothermally prepared under identical conditions without Cu-HHTP. | SI text · S1.1.2. Synthesis of V3O7.H2O and VO@Cu-HHTP |