Spectroscopy — Conductive Metal–Organic Frameworks Anchoring on V3O7·H2O Nanobelts Toward High-Capacity and Long-Life Zinc-Ion Batteries

3 measurement groups · 27 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

VO@Cu-HHTP-2 composite cathode electrode · Electrode

VO@Cu-HHTP-2 samples in fully charged and discharged states; TEM/HRTEM after discharging to 0.2 V and charging to 1.6 V.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Charged-state (002) lattice spacing	0.181 nm	—	—	Text Exact Reported	p008 · 2.3 · Figure 5g
Discharged-state (101) lattice spacing	0.208 nm	—	—	Text Exact Reported	p008 · 2.3 · Figure 5e
Zn 2p1/2 binding energy after discharge	1045.1 eV	—	—	Text Exact Reported	p007-p008 · 2.3 · Figure 5c
Zn 2p3/2 binding energy after discharge	1022.1 eV	—	—	Text Exact Reported	p007-p008 · 2.3 · Figure 5c

VO@Cu-HHTP-2 · Nanosheet

Raman spectra measured over 100-1750 cm-1.

Context: VO@Cu-HHTP-2 composite
Measurement source: p002 · 2.1. Structural and Morphological Characterization · Figure 1b

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Cu-HHTP benzene skeleton Raman band	1370.6 cm-1	—	—	Text Exact Reported	p002 · 2.1 · Figure 1b
Cu-HHTP benzene skeleton Raman band	1580.1 cm-1	—	—	Text Exact Reported	p002 · 2.1 · Figure 1b
Layered-structure Bg Raman mode	139.4 cm-1	—	—	Text Exact Reported	p002 · 2.1 · Figure 1b
O3-V=O stretching Raman mode	286.2 cm-1	—	—	Text Exact Reported	p002 · 2.1 · Figure 1b
V2-O Raman band	686.9 cm-1	—	—	Text Exact Reported	p002 · 2.1 · Figure 1b
V3-O Raman band	506.1 cm-1	—	—	Text Exact Reported	p002 · 2.1 · Figure 1b
V-O3-V stretching Raman mode	408.7 cm-1	—	—	Text Exact Reported	p002 · 2.1 · Figure 1b
V=O stretching Raman band	995.3 cm-1	—	—	Text Exact Reported	p002 · 2.1 · Figure 1b

VO@Cu-HHTP-2 · Nanosheet

V 2p, O 1s, N 1s, Cu 2p, and C 1s spectra for VO and VO@Cu-HHTP-2.

Context: target composite compared with pristine VO control
Measurement source: SI text · S1.2 Materials characterization · Figure 1d-f; Figure S2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
C 1s C=O component	288.9 eV	—	—	Text Exact Reported	p003 · 2.1 · Figure S2
C 1s C-OH component	286.2 eV	—	—	Text Exact Reported	p003 · 2.1 · Figure S2
C 1s C-C component	284.8 eV	—	—	Text Exact Reported	p003 · 2.1 · Figure S2
Cu 2p1/2 binding energy	951.3 eV	—	—	Text Exact Reported	p003 · 2.1 · Figure 1d-f
Cu 2p3/2 binding energy	931.8 eV	—	—	Text Exact Reported	p003 · 2.1 · Figure 1f
N 1s -NH2 binding energy	401.3 eV	—	—	Text Exact Reported	p003 · 2.1 · Figure 1d-f
N-V N 1s binding energy	399.6 eV	—	—	Text Exact Reported	p003 · 2.1 · Figure 1f
O 1s H2O component	533.5 eV	—	—	Text Exact Reported	p003 · 2.1 · Figure 1d-f
O 1s OH- component	531.7 eV	—	—	Text Exact Reported	p003 · 2.1 · Figure 1d-f
O 1s V-O component	530.1 eV	—	—	Text Exact Reported	p003 · 2.1 · Figure 1e
V4+ V 2p1/2 binding energy	523.5 eV	—	—	Text Exact Reported	p003 · 2.1 · Figure 1d-f
V4+ V 2p3/2 binding energy	516.2 eV	—	—	Text Exact Reported	p003 · 2.1 · Figure 1d
V5+ V 2p1/2 binding energy	524.9 eV	—	—	Text Exact Reported	p003 · 2.1 · Figure 1d-f
V5+ V 2p3/2 binding energy	517.7 eV	—	—	Text Exact Reported	p003 · 2.1 · Figure 1d
V5+ binding-energy shift after Cu-HHTP anchoring	517.7 to 517.4 eV	—	—	Text Exact Reported	p003 · 2.1 · Figure 1d