Microscopy Morphology

SEM, TEM, high-resolution TEM and SAED

Co-DAPV thin film on glass, 8 LbL cycles · Thin Film

Top-view and cross-sectional SEM of Co-DAPV film on glass; TEM/HRTEM/SAED of film sheets.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Co-DAPV film morphology	large MOF sheets / large thin sheet form	—	—	Text Qualitative	12931 · Results · Figure 1a
HRTEM/SAED crystallinity	single-crystalline nature of the MOF film	—	—	Text Qualitative	12931 · Results · Figure 1c
Co-DAPV film thickness after 8 LbL cycles	approximately 140 nm in 8 LbL deposition cycles	—	approximately	Text Approximate	12931 · Results · Figure 1b

2000 rpm TiO2/Co-DAPV device series, 5-30 LbL cycles · Electrode

Optimised photoanode cross-section and top views before/after Co-DAPV sensitisation.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
optimised Co-DAPV overlay thickness	about 300 nm thick overlay of Co-DAPV layer	—	about	Caption Approximate	12932 · Figure 3 caption · Figure 3b
optimised TiO2 blocking layer thickness	about 50 nm thick TiO2 blocking layer	—	about	Caption Approximate	12932 · Figure 3 caption · Figure 3b
optimised mesoporous TiO2 thickness	about 500 nm thick mesoporous TiO2 film	—	about	Caption Approximate	12932 · Figure 3 caption · Figure 3b
Co-DAPV on optimised photoanode morphology	large thin sheets with similar morphology as Figure 1a	—	—	Text Qualitative	12933 · Results · Figure S7