Electrical Transport — Encapsulating metal organic framework into hollow mesoporous carbon sphere as efficient oxygen bifunctional electrocatalyst

Measurement evidence

Electrical Transport

Encapsulating metal organic framework into hollow mesoporous carbon sphere as efficient oxygen bifunctional electrocatalyst · Xiong W., Li H., You H. et al. · National Science Review · 2020 · 609-619

5 measurement groups · 22 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Electrochemical impedance spectroscopy (EIS) fitted with equivalent circuit

HMCS · Powder

EIS performed at open circuit voltage with 5 mV disturbance; fitted high-frequency range 100 kHz to 100 Hz using equivalent circuit.

Context
Electrochemical charge-transfer/transport comparison.
Measurement source
SI p. 9 · Supplementary Tables · Table S3
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
HMCS charge-transfer resistance RctMarked as a best value within this paper2.47 ohmrel. std. error 3.319%SI Table
Exact Reported
SI p. 9 · Supplementary Tables · Table S3
HMCS Rct relative standard error3.319%SI Table
Exact Reported
SI p. 9 · Supplementary Tables · Table S3
HMCS EIS solution resistance Rs41.03 ohmrel. std. error 0.164%SI Table
Exact Reported
SI p. 9 · Supplementary Tables · Table S3
HMCS Rs relative standard error0.164%SI Table
Exact Reported
SI p. 9 · Supplementary Tables · Table S3

Electrochemical impedance spectroscopy (EIS) fitted with equivalent circuit

pure ZIF-67 · Powder

EIS performed at open circuit voltage with 5 mV disturbance; fitted high-frequency range 100 kHz to 100 Hz using equivalent circuit.

Geometry
RDE electrode in electrolyte
Context
Electrochemical charge-transfer/transport comparison.
Measurement source
SI p. 9 · Supplementary Tables · Table S3
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Charge transfer resistance Rct of ZIF-6733.87 ohmSI Table
Exact Reported
SI p. 9 · Supplementary Tables · Table S3
ZIF-67 Rct relative standard error24.6%SI Table
Exact Reported
SI p. 9 · Supplementary Tables · Table S3
ZIF-67 charge-transfer resistance Rct33.87 ohmrel. std. error 24.6%SI Table
Exact Reported
SI p. 9 · Supplementary Tables · Table S3
ZIF-67 Rs relative standard error0.924%SI Table
Exact Reported
SI p. 9 · Supplementary Tables · Table S3
ZIF-67 EIS solution resistance Rs49.5 ohmrel. std. error 0.924%SI Table
Exact Reported
SI p. 9 · Supplementary Tables · Table S3

Electrochemical impedance spectroscopy (EIS) fitted with equivalent circuit

ZIF@HMCS-10% · Powder

EIS performed at open circuit voltage with 5 mV disturbance; fitted high-frequency range 100 kHz to 100 Hz using equivalent circuit.

Context
Electrochemical charge-transfer/transport comparison.
Measurement source
SI p. 9 · Supplementary Tables · Table S3
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
ZIF@HMCS-10% Rct relative standard error16.5%SI Table
Exact Reported
SI p. 9 · Supplementary Tables · Table S3
ZIF@HMCS-10% charge-transfer resistance Rct9.01 ohmrel. std. error 16.5%SI Table
Exact Reported
SI p. 9 · Supplementary Tables · Table S3
ZIF@HMCS-10% Rs relative standard error0.185%SI Table
Exact Reported
SI p. 9 · Supplementary Tables · Table S3
ZIF@HMCS-10% EIS solution resistance Rs43.9 ohmrel. std. error 0.185%SI Table
Exact Reported
SI p. 9 · Supplementary Tables · Table S3

Electrochemical impedance spectroscopy (EIS) fitted with equivalent circuit

ZIF@HMCS-25% catalyst ink electrode · Electrode

EIS performed at open circuit voltage with 5 mV disturbance; fitted high-frequency range 100 kHz to 100 Hz using equivalent circuit.

Geometry
RDE electrode in electrolyte
Context
Electrochemical charge-transfer/transport comparison.
Measurement source
SI p. 9 · Supplementary Tables · Table S3
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Charge transfer resistance Rct of ZIF@HMCS-25%3.58 ohmSI Table
Exact Reported
SI p. 9 · Supplementary Tables · Table S3
ZIF@HMCS-25% Rct relative standard error5.72%SI Table
Exact Reported
SI p. 9 · Supplementary Tables · Table S3
ZIF@HMCS-25% charge-transfer resistance Rct3.58 ohmrel. std. error 5.72%SI Table
Exact Reported
SI p. 9 · Supplementary Tables · Table S3
ZIF@HMCS-25% Rs relative standard error0.105%SI Table
Exact Reported
SI p. 9 · Supplementary Tables · Table S3
ZIF@HMCS-25% EIS solution resistance Rs44.3 ohmrel. std. error 0.105%SI Table
Exact Reported
SI p. 9 · Supplementary Tables · Table S3

Electrochemical impedance spectroscopy (EIS) fitted with equivalent circuit

ZIF@HMCS-50% · Powder

EIS performed at open circuit voltage with 5 mV disturbance; fitted high-frequency range 100 kHz to 100 Hz using equivalent circuit.

Context
Electrochemical charge-transfer/transport comparison.
Measurement source
SI p. 9 · Supplementary Tables · Table S3
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
ZIF@HMCS-50% Rct relative standard error3.86%SI Table
Exact Reported
SI p. 9 · Supplementary Tables · Table S3
ZIF@HMCS-50% charge-transfer resistance Rct2.93 ohmrel. std. error 3.86%SI Table
Exact Reported
SI p. 9 · Supplementary Tables · Table S3
ZIF@HMCS-50% Rs relative standard error0.15%SI Table
Exact Reported
SI p. 9 · Supplementary Tables · Table S3
ZIF@HMCS-50% EIS solution resistance Rs45.01 ohmrel. std. error 0.15%SI Table
Exact Reported
SI p. 9 · Supplementary Tables · Table S3