Karazan Z.M., Roushani M. · Electrocatalysis · 2024 · 110-119
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
Ni/Mn-MOF/GCE provides amperometric OSIM sensing with two wide linear ranges, 0.16 uM LOD, selectivity against tested interferents, reproducibility, repeatability and stability.
Caveat: Performance is application-specific for OSIM in alkaline electrolyte; no independent validation dataset is provided.
p008-p009 · Amperometric Sensing; Selectivity; Stability · Fig. 6-Fig. 8 · Linked to 6 structured results
The Ni/Mn-MOF/GCE sensor was applied to OSIM detection in serum samples with recoveries of 98 to 101.71% and RSD below or equal to 1.31%.
Caveat: The table's found concentrations exceed added spike values for several rows, so raw table values should be interpreted as reported total found concentration/standard-addition output.
p009 · MOF/GCE Performance in the Actual Sample · Table 1 · Linked to 3 structured results
FESEM, EDS/EDX and XRD support successful synthesis of crystalline Ni/Mn-MOF with C, O, Mn and Ni present and no metal oxide/hydroxide impurity peaks detected by XRD.
Caveat: No empirical formula, elemental percentages, BET porosity, CIF or full structure refinement are reported.
p003 · Morphological Studies · Fig. 2-Fig. 4 · Linked to 3 structured results
The porous spherical Ni/Mn-MOF morphology is proposed to increase surface area and facilitate fast electrolyte-ion transfer to the electrode surface.
Caveat: Surface area and ion-diffusion coefficients were not measured directly.
p003 · Morphological Studies · Fig. 2g-l · Linked to 1 structured result
OSIM oxidation on Ni/Mn-MOF/GCE is described as diffusion-controlled because oxidation peak current varies linearly with the square root of scan rate.
Caveat: The reported regression is for peak current versus square-root scan rate; raw data are graphical.
p006 · Cyclic Voltammetric Responses of OSIM · Fig. 5E · Linked to 1 structured result
Ni/Mn-MOF/GCE shows higher electrocatalytic response than bare GCE for OSIM oxidation, attributed to Ni/Mn redox reactions, enlarged surface area and good conductivity.
Caveat: No four-probe or direct electronic conductivity measurement is reported; conductivity is inferred from electrochemical response.
p006 · Cyclic Voltammetric Responses of OSIM · Fig. 5A-C · Linked to 2 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| bare glassy carbon electrode | Cnone · none | 0D · Model SystemCommercial/standard glassy carbon working electrode used as electrochemical control. | p002 · Materials and Instruments |
| Mn-MOF morphology control | not reportedMn centres · not explicitly stated for this control; context suggests TPA-based MOF | unknown · PristineHomogeneous laminar Mn-MOF morphology observed by FESEM. | p003 · Morphological Studies · Fig. 2a-c |
| Ni/Mn bimetal-organic framework | not reportedNi and Mn centres from Ni(NO3)2.6H2O and MnCl2; electrochemical discussion invokes Ni(II)/Ni(III) and Mn(II)/Mn(IV) redox couples · terephthalic acid (TPA) | unknown · PristineCrystalline bimetallic MOF with monoclinic Ni-MOF-like XRD peaks and porous spheroidal morphology. | p001 · Abstract |
| Ni/Mn-MOF modified glassy carbon electrode | not applicableNi/Mn-MOF active component on glassy carbon electrode · TPA in the Ni/Mn-MOF component | unknown · CompositeComposite electrode formed by drop-casting Ni/Mn-MOF suspension onto GCE and electrochemical activation in NaOH. | p003 · Fabrication of the Modified GCE |
| Ni-MOF morphology control | not reportedNi centres · TPA | unknown · PristineNi-MOF microspheres with smooth surface observed by FESEM. | p003 · Morphological Studies · Fig. 2d-f |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| bare GCEresearch_0268__mat__mat_bare_gce | Electrode · Pristine Control · Model | Polished and cleaned GCE used without MOF modification.glassy carbon electrode | p006 · Cyclic Voltammetric Responses of OSIM · Fig. 5A,C |
| Mn-MOF powderresearch_0268__mat__mat_mn_mof | Powder · Pristine Control · Pristine Framework | Not reported in this article. | p004 · Figure caption · Fig. 2a-c |
| Ni/Mn-MOF/GCEresearch_0268__mat__mat_ni_mn_mof_gce | Electrode · Composite Sample · Composite | GCE polished, cleaned, coated with 10 uL of 1 mg mL-1 Ni/Mn-MOF in DMF, dried at room temperature, rinsed and activated by 15 CV cycles in 0.1 M NaOH.glassy carbon electrode | p003 · Fabrication of the Modified GCE |
| green Ni/Mn-MOF powderresearch_0268__mat__mat_ni_mn_mof | Powder · Target Sample · Mixed Metal | Solvothermal product rinsed with ethanol and DMF, then dried overnight at 50 C. | p003 · Synthesis of Ni/Mn-MOF · Scheme 1 |
| Ni-MOF powderresearch_0268__mat__mat_ni_mof | Powder · Pristine Control · Pristine Framework | Not reported in this article. | p004 · Figure caption · Fig. 2d-f |