Gao W., Chen D., Quan H. et al. · ACS Sustainable Chemistry and Engineering · 2017 · 4144-4153
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
The PC//HP-UiO-66 asymmetric supercapacitor delivers 32 W h kg-1 at 240 W kg-1 and maintains useful performance at high power.
Caveat: Device performance depends on porous carbon negative electrode as well as HP-UiO-66 positive electrode.
p007 · Electrochemical Properties of PC//HP-UiO-66 ASC · Figure 6e · Linked to 4 structured results
Bare UiO-66 is described as having low conductivity and weak alkaline stability, motivating hierarchical porous modification.
Caveat: The low conductivity statement cites prior literature and is not supported by direct conductivity measurement in this article.
p007 · Electrochemical Behaviors · Linked to 2 structured results
Hierarchical micro/mesoporosity, higher surface area, larger pore volume, and surface defects are proposed to improve ion/electrolyte access and electrochemical performance.
Caveat: The performance is measured on composite electrodes containing carbon black, so intrinsic MOF conductivity is not isolated.
p007 · Electrochemical Behaviors · Linked to 5 structured results
Higher oxygen and zirconium surface contents suggest unsaturated Zr4+ defects on HP-UiO-66, which the authors link to improved capacitance.
Caveat: Defect density is inferred from XPS/TGA and not quantified directly.
p004 · Structure and Morphology · Table 1 · Linked to 3 structured results
HP-UiO-66 is formed by synthesising bimetallic Zn/Zr MOFs and removing acid-sensitive Zn-MOF domains in acid solution.
Caveat: SI Figure S2 provides only a qualitative SEM image of the Zn/Zr precursor; no additional quantitative precursor morphology is reported.
p003 · Structure and Morphology · Figure 1 · Linked to 3 structured results
Lower fitted Rs and Rct for HP-UiO-66 than UiO-66 indicate improved electrode/electrolyte charge transport and higher effective conductivity.
Caveat: EIS fitting is from a slurry composite electrode, not a direct intrinsic electrical conductivity measurement of the MOF powder.
p007 · Electrochemical Behaviors · Figure 5f · Linked to 4 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| Hierarchical porous UiO-66 (HP-UiO-66) | Zr-based UiO-66 with hierarchical micro/mesoporosity; empirical formula not reportedZr · H2BDC / terephthalate | 3D · PristineHierarchical porous UiO-66 obtained by removing Zn-MOF domains from bimetallic Zn/Zr MOFs. | p001 · Abstract |
| PC//HP-UiO-66 asymmetric supercapacitor | Porous carbon negative electrode // HP-UiO-66 positive electrodeZr in HP-UiO-66 positive electrode · H2BDC / terephthalate in HP-UiO-66 | unknown · CompositeAsymmetric supercapacitor device assembled from porous carbon and HP-UiO-66 electrodes. | p007 · Electrochemical Properties of PC//HP-UiO-66 Asymmetric Supercapacitor · Figure 6a |
| Biomass-derived porous carbon | C | unknown · DerivedPorous carbon negative-electrode material cited from prior work and used in the asymmetric supercapacitor. | p002 · Electrochemical Measurements |
| Bare UiO-66 | Zr-based UiO-66; empirical formula not reportedZr · H2BDC / terephthalate | 3D · PristineUiO-66 Zr-MOF phase, matched simulated and reported UiO-66 XRD patterns. | p002 · Experimental Section |
| Bimetallic Zn/Zr MOFs precursor | Zn/Zr MOFs; MOF-5/UiO-66-related precursor mixture; empirical formula not reportedZn and Zr · H2BDC / terephthalate | 3D · PristineBimetallic Zn/Zr MOF precursor formed before acid removal of acid-sensitive Zn-MOF domains. | p003 · Results and Discussion · Figure 1 |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| HP-UiO-66 working electroderesearch_0298__mat__hp_uio66 | Electrode · Target Sample · Composite | Slurry-coated electrode containing active HP-UiO-66, carbon black, and PVDF.Ni foam | p002 · Electrochemical Measurements |
| HP-UiO-66 powderresearch_0298__mat__hp_uio66 | Powder · Target Sample · Pristine Framework | Acid-etched hierarchical porous UiO-66, washed and dried. | p002 · Experimental Section |
| PC//HP-UiO-66 ASCresearch_0298__mat__pc_hp_uio66_asc | Electrode · Composite Sample · Composite | HP-UiO-66 positive electrode and biomass-derived porous carbon negative electrode separated by polypropylene membrane.two-electrode asymmetric supercapacitor | p002 · Electrochemical Measurements |
| Porous carbon negative electroderesearch_0298__mat__porous_carbon | Electrode · Composite Component · Derived Carbon | Biomass-derived porous carbon electrode used as the negative electrode in PC//HP-UiO-66 ASC.asymmetric supercapacitor negative electrode | p002 · Electrochemical Measurements |
| Bare UiO-66 working electroderesearch_0298__mat__uio66 | Electrode · Pristine Control · Composite | Slurry-coated electrode containing active UiO-66, carbon black, and PVDF.Ni foam | p002 · Electrochemical Measurements |
| Bare UiO-66 powderresearch_0298__mat__uio66 | Powder · Pristine Control · Pristine Framework | Solvothermal Zr-MOF product, washed and dried. | p002 · Experimental Section |
| Zn/Zr MOFs precursorresearch_0298__mat__zn_zr_mof_precursor | Powder · Unknown · Mixed Metal | Hybrid MOF precipitate before acid etching. | p002 · Experimental Section |