cMOF Evidence Base

Synthesis evidence

Negative electrodes for supercapacitors with good performance using conductive bismuth-catecholate metal-organic frameworks

Chen S., Zhang H., Li X. et al. · Dalton Transactions · 2023 · 4826-4834

5 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Complete recipeSource: Both

Route 1: Hydrothermal

p002 / article p.4827 · Synthesis of Bi(HHTP) nanobelts · Scheme 1

Metal precursorsbismuth(III) acetate, 93 mg
Linker precursors2,3,6,7,10,11-hexahydroxytriphenylene, 40 mg
Solvents40 mL deionized water; workup with acetone, absolute ethanol and deionized water
Atmospherenot specified
Temperature85
Time12
Work-upCentrifugally purified with acetone, absolute ethanol and deionized water.
ActivationDried for 12 h at 60 C in a vacuum oven.
Scalability contextSingle 50 mL container batch; no scale-up study reported.
Show 5 structured reagent records
RoleReagentAmount / concentrationSource
Metal Sourcebismuth(III) acetate93 mg · >=99.9%p002 / article p.4827 · Synthesis of Bi(HHTP) nanobelts · Scheme 1
Linker2,3,6,7,10,11-hexahydroxytriphenylene40 mg · 98%p002 / article p.4827 · Synthesis of Bi(HHTP) nanobelts · Scheme 1
Solventdeionized water40 mLp002 / article p.4827 · Synthesis of Bi(HHTP) nanobelts · Scheme 1
Solventacetonewash solvent · >=99.5%p002 / article p.4827 · Synthesis of Bi(HHTP) nanobelts · Scheme 1
Solventethyl alcohol absolutewash solvent · >=99.7%p002 / article p.4827 · Synthesis of Bi(HHTP) nanobelts · Scheme 1
Complete recipeSource: Both

Route 2: Hydrothermal

p002 / article p.4827 · Synthesis of Bi(HHTP) nanobelts · Scheme 1

Metal precursorsbismuth(III) acetate, 93 mg
Linker precursors2,3,6,7,10,11-hexahydroxytriphenylene, 40 mg
Solvents40 mL deionized water; workup with acetone, absolute ethanol and deionized water
Atmospherenot specified
Temperature85
Time20
Work-upCentrifugally purified with acetone, absolute ethanol and deionized water.
ActivationDried for 12 h at 60 C in a vacuum oven.
Scalability contextSingle 50 mL container batch; no scale-up study reported.
Show 5 structured reagent records
RoleReagentAmount / concentrationSource
Metal Sourcebismuth(III) acetate93 mg · >=99.9%p002 / article p.4827 · Synthesis of Bi(HHTP) nanobelts · Scheme 1
Linker2,3,6,7,10,11-hexahydroxytriphenylene40 mg · 98%p002 / article p.4827 · Synthesis of Bi(HHTP) nanobelts · Scheme 1
Solventdeionized water40 mLp002 / article p.4827 · Synthesis of Bi(HHTP) nanobelts · Scheme 1
Solventacetonewash solvent · >=99.5%p002 / article p.4827 · Synthesis of Bi(HHTP) nanobelts · Scheme 1
Solventethyl alcohol absolutewash solvent · >=99.7%p002 / article p.4827 · Synthesis of Bi(HHTP) nanobelts · Scheme 1
Complete recipeSource: Both

Route 3: Hydrothermal

p002 / article p.4827 · Synthesis of Bi(HHTP) nanobelts · Scheme 1

Metal precursorsbismuth(III) acetate, 93 mg
Linker precursors2,3,6,7,10,11-hexahydroxytriphenylene, 40 mg
Solvents40 mL deionized water; workup with acetone, absolute ethanol and deionized water
Atmospherenot specified
Temperature85
Time4
Work-upCentrifugally purified with acetone, absolute ethanol and deionized water.
ActivationDried for 12 h at 60 C in a vacuum oven.
Scalability contextSingle 50 mL container batch; no scale-up study reported.
Show 5 structured reagent records
RoleReagentAmount / concentrationSource
Metal Sourcebismuth(III) acetate93 mg · >=99.9%p002 / article p.4827 · Synthesis of Bi(HHTP) nanobelts · Scheme 1
Linker2,3,6,7,10,11-hexahydroxytriphenylene40 mg · 98%p002 / article p.4827 · Synthesis of Bi(HHTP) nanobelts · Scheme 1
Solventdeionized water40 mLp002 / article p.4827 · Synthesis of Bi(HHTP) nanobelts · Scheme 1
Solventacetonewash solvent · >=99.5%p002 / article p.4827 · Synthesis of Bi(HHTP) nanobelts · Scheme 1
Solventethyl alcohol absolutewash solvent · >=99.7%p002 / article p.4827 · Synthesis of Bi(HHTP) nanobelts · Scheme 1
Complete recipeSource: Both

Route 4: Hydrothermal

p002 / article p.4827 · Synthesis of Bi(HHTP) nanobelts · Scheme 1

Metal precursorsbismuth(III) acetate, 93 mg
Linker precursors2,3,6,7,10,11-hexahydroxytriphenylene, 40 mg
Solvents40 mL deionized water; workup with acetone, absolute ethanol and deionized water
Atmospherenot specified
Temperature85
Time8
Work-upCentrifugally purified with acetone, absolute ethanol and deionized water.
ActivationDried for 12 h at 60 C in a vacuum oven.
Scalability contextSingle 50 mL container batch; no scale-up study reported.
Show 5 structured reagent records
RoleReagentAmount / concentrationSource
Metal Sourcebismuth(III) acetate93 mg · >=99.9%p002 / article p.4827 · Synthesis of Bi(HHTP) nanobelts · Scheme 1
Linker2,3,6,7,10,11-hexahydroxytriphenylene40 mg · 98%p002 / article p.4827 · Synthesis of Bi(HHTP) nanobelts · Scheme 1
Solventdeionized water40 mLp002 / article p.4827 · Synthesis of Bi(HHTP) nanobelts · Scheme 1
Solventacetonewash solvent · >=99.5%p002 / article p.4827 · Synthesis of Bi(HHTP) nanobelts · Scheme 1
Solventethyl alcohol absolutewash solvent · >=99.7%p002 / article p.4827 · Synthesis of Bi(HHTP) nanobelts · Scheme 1
Complete recipeSource: Main

Route 5: Other

p003 / article p.4828 · Electrochemical measurements

Metal precursorspre-synthesised Bi(HHTP) active material
Solvents1-methyl-2-pyrrolidene
AdditivesSuper-P conductive carbon black; polyvinylidene fluoride binder
Atmospherenot specified during slurry coating; vacuum oven drying
Temperature60
Time0.5 h milling plus 12 h drying
Substrate orientationclean carbon cloth substrate
Work-upMilled into slurry, smeared on carbon cloth, and dried.
ActivationElectrodes immersed in alkaline electrolyte for 1 h before testing.
Scalability contextConventional slurry coating; no scale-up or electrode-area details beyond mass loading.
Show 5 structured reagent records
RoleReagentAmount / concentrationSource
OtherBi(HHTP) active material16 mgp003 / article p.4828 · Electrochemical measurements
AdditiveSuper-P conductive carbon black2 mg · >99%p003 / article p.4828 · Electrochemical measurements
Additivepolyvinylidene fluoride2 mgp003 / article p.4828 · Electrochemical measurements
Solvent1-methyl-2-pyrrolidenesolution · >=99.9%p003 / article p.4828 · Electrochemical measurements
Othercarbon clothsubstratep003 / article p.4828 · Electrochemical measurements