cMOF Evidence Base
Diffraction Structure — Cofacial Assembly of Metallomacrocycles as an Approach to Controlling Lattice Architecture in Low-Dimensional Molecular Solids. Chemical, Structural, Oxidation-State, Transport, and Optical Properties of the Coordination Polymer [Fe(phthalocyaninato)(μ-pyrazine)]n and the Consequences of Halogen Doping

Measurement evidence

Diffraction Structure

Cofacial Assembly of Metallomacrocycles as an Approach to Controlling Lattice Architecture in Low-Dimensional Molecular Solids. Chemical, Structural, Oxidation-State, Transport, and Optical Properties of the Coordination Polymer [Fe(phthalocyaninato)(μ-pyrazine)]n and the Consequences of Halogen Doping · Diel B.N., Inabe T., Jaggi N.K. et al. · Journal of the American Chemical Society · 1984 · 3207-3214

2 measurement groups · 3 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

powder X-ray diffraction

X-ray diffraction and scattering

{[Fe(Pc)(mu-pyz)]I2.54}n, eq 5 · Pellet

Incremental iodination followed by powder X-ray diffraction; repeated benzene washing tested reversibility.

Geometry
pressed powder pellets
Context
doped target samples compared with pristine phase
Measurement source
3210 · Iodine Doping Process
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
high-y doped polymer diffraction patternby y approximately 2, only a broad, diffuse diffraction pattern is observed——Text
Qualitative		3210 · Iodine Doping Process

powder X-ray diffraction

X-ray diffraction and scattering

Table III pristine mu-pyrazine polymer PXRD series · Pellet

Graphite-monochromated, Ni-filtered Co or Cr Kalpha radiation; pressed powders in 13 mm pellets; scan rate 0.25 deg/min.

Geometry
pressed powder pellets 13 mm diameter and 1-2 mm thick
Context
pristine solvent-included polymer phases
Measurement source
3209 · X-ray Diffraction · Table III
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
PXRD d-spacings for {[Fe(Pc)(pyz)]-0.5C6H6}n13.59 m; 7.45 vw; 6.27 m; 5.80 m; 4.14 vw; 3.42 w; 3.14 vw——Table
Exact Reported		3209 · Results · Table III
PXRD d-spacings for {[Fe(Pc)(pyz)]-0.3C6H5Cl}n18.50 w; 15.92 vw; 13.55 s; 12.34 vs; 10.12 vw; 6.76 w; 6.14 m; 5.45 w; 4.51 w; 4.11 w; 3.75 w; 3.41 m; 3.20 vw; 3.09 w——Table
Exact Reported		3209 · Results · Table III