Measurement evidence
Cofacial Assembly of Metallomacrocycles as an Approach to Controlling Lattice Architecture in Low-Dimensional Molecular Solids. Chemical, Structural, Oxidation-State, Transport, and Optical Properties of the Coordination Polymer [Fe(phthalocyaninato)(μ-pyrazine)]n and the Consequences of Halogen Doping · Diel B.N., Inabe T., Jaggi N.K. et al. · Journal of the American Chemical Society · 1984 · 3207-3214
Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.
{[Fe(Pc)(mu-pyz)]I2.10}n, eq 4 · Pellet
100 microA passed through a 9.6 mg pellet for 80 h to check possible ion conduction.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| conductivity decrease during blocking-electrode ion-conduction test | less than 1.2% | — | upper bound | Text Approximate | 3209 · Charge-Transport Measurements |
[Fe(Pc)(mu-pyz)]n prepared by eq 2 · Pellet
Undoped [Fe(Pc)(mu-pyz)]n samples prepared by eq 2 or eq 3; plotted as conductivity versus 10^3/T.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| room-temperature conductivity range for undoped [Fe(Pc)(pyz)]n | on the order of 10^-6-10^-7 ohm^-1 cm^-1 | — | — | Text Range | 3212 · Doped Polymers. Charge Transport · Figure 5 |
{[Fe(Pc)(mu-pyz)]I2.60}n · Pellet
Conductivity data for 14-180 K plotted as -[ln(sigma/sigma0)]^-1 versus T and fitted over visually linear intervals from 14-110 K to 14-150 K.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| fluctuation-induced tunnelling sigma0 | sigma0 = 0.155 (4) ohm^-1 cm^-1 | — | (4) | Text Exact Reported | 3213 · Doped Polymers. Charge Transport · Figure 9 |
| fluctuation-induced tunnelling T0 | T0 = 7.6 (2) deg | — | (2) | Text Exact Reported | 3213 · Doped Polymers. Charge Transport · Figure 9 |
| fluctuation-induced tunnelling T1 | T1 = 460 (4) deg | — | (4) | Text Exact Reported | 3213 · Doped Polymers. Charge Transport · Figure 9 |
Table VI pressed-powder transport series · Pellet
Pressed powder compactions measured from 77 to 320 K; activation energies from least-squares fits to thermal activation model over 96-300 K.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| activation energy, {[Fe(Pc)(pyz)]I0.19}n eq 4 | 0.139 eV | — | — | Table Exact Reported | 3212 · Doped Polymers. Charge Transport · Table VI |
| activation energy, {[Fe(Pc)(pyz)]I0.38}n eq 4 | 0.116 eV | — | — | Table Exact Reported | 3212 · Doped Polymers. Charge Transport · Table VI |
| activation energy, {[Fe(Pc)(pyz)]I0.77}n eq 4 | 0.079 eV | — | — | Table Exact Reported | 3212 · Doped Polymers. Charge Transport · Table VI |
| activation energy, {[Fe(Pc)(pyz)]I2.10}n eq 4 | 0.080 eV | — | — | Table Exact Reported | 3212 · Doped Polymers. Charge Transport · Table VI |
| activation energy, {[Fe(Pc)(pyz)]I2.76}n eq 4 | 0.065 eV | — | — | Table Exact Reported | 3212 · Doped Polymers. Charge Transport · Table VI |
| activation energy, {[Fe(Pc)(pyz)]I0.38}n eq 5 | 0.141 eV | — | — | Table Exact Reported | 3212 · Doped Polymers. Charge Transport · Table VI |
| activation energy, {[Fe(Pc)(pyz)]I1.49}n eq 5 | 0.053 eV | — | — | Table Exact Reported | 3212 · Doped Polymers. Charge Transport · Table VI |
| activation energy, {[Fe(Pc)(pyz)]I2.10}n eq 5Marked as a best value within this paper | 0.033 eV | — | — | Table Exact Reported | 3212 · Doped Polymers. Charge Transport · Table VI |
| activation energy, {[Fe(Pc)(pyz)]I2.54}n eq 5 | 0.045 eV | — | — | Table Exact Reported | 3212 · Doped Polymers. Charge Transport · Table VI |
| activation energy, pristine [Fe(Pc)(pyz)]n sample B | 0.404 eV | — | — | Table Exact Reported | 3212 · Doped Polymers. Charge Transport · Table VI |
| maximum conductivity increase upon iodine doping | up to 10^6 | — | — | Text Approximate | 3207 · Abstract |
| sigma_RT, {[Fe(Pc)(pyz)]I0.19}n eq 4 | 9.31 x 10^-4 ohm^-1 cm^-1 | — | — | Table Exact Reported | 3212 · Doped Polymers. Charge Transport · Table VI |
| sigma_RT, {[Fe(Pc)(pyz)]I0.38}n eq 4 | 2.58 x 10^-3 ohm^-1 cm^-1 | — | — | Table Exact Reported | 3212 · Doped Polymers. Charge Transport · Table VI |
| sigma_RT, {[Fe(Pc)(pyz)]I0.77}n eq 4 | 8.63 x 10^-3 ohm^-1 cm^-1 | — | — | Table Exact Reported | 3212 · Doped Polymers. Charge Transport · Table VI |
| sigma_RT, {[Fe(Pc)(pyz)]I2.10}n eq 4 | 7.55 x 10^-3 ohm^-1 cm^-1 | — | — | Table Exact Reported | 3212 · Doped Polymers. Charge Transport · Table VI |
| sigma_RT, {[Fe(Pc)(pyz)]I2.76}n eq 4 | 2.33 x 10^-2 ohm^-1 cm^-1 | — | — | Table Exact Reported | 3212 · Doped Polymers. Charge Transport · Table VI |
| sigma_RT, {[Fe(Pc)(pyz)]I0.38}n eq 5 | 4.60 x 10^-4 ohm^-1 cm^-1 | — | — | Table Exact Reported | 3212 · Doped Polymers. Charge Transport · Table VI |
| sigma_RT, {[Fe(Pc)(pyz)]I1.49}n eq 5 | 5.99 x 10^-3 ohm^-1 cm^-1 | — | — | Table Exact Reported | 3212 · Doped Polymers. Charge Transport · Table VI |
| sigma_RT, {[Fe(Pc)(pyz)]I2.10}n eq 5 | 1.28 x 10^-1 ohm^-1 cm^-1 | — | — | Table Exact Reported | 3212 · Doped Polymers. Charge Transport · Table VI |
| sigma_RT, {[Fe(Pc)(pyz)]I2.54}n eq 5Marked as a best value within this paper | 1.90 x 10^-1 ohm^-1 cm^-1 | — | — | Table Exact Reported | 3212 · Doped Polymers. Charge Transport · Table VI |
| sigma_RT, pristine [Fe(Pc)(pyz)]n sample B | 7.79 x 10^-8 ohm^-1 cm^-1 | — | — | Table Exact Reported | 3212 · Doped Polymers. Charge Transport · Table VI |