Electrochemistry Application — Porous Molecular Conductor: Electrochemical Fabrication of Through-Space Conduction Pathways among Linear Coordination Polymers

Measurement evidence

Electrochemistry Application

Porous Molecular Conductor: Electrochemical Fabrication of Through-Space Conduction Pathways among Linear Coordination Polymers · Qu L., Iguchi H., Takaishi S. et al. · Journal of the American Chemical Society · 2019 · 6802-6806

2 measurement groups · 4 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Solid-state cyclic voltammetry, LiClO4 electrolyte

Voltammetry

PMC-1 bulk powder/crystals · Powder

PMC-1-modified glassy carbon electrode; 0.1 M LiClO4 in CH3CN; scan rate 100 mV/s; Pt counter and Ag quasi-reference; Fc/Fc+ calibration.

Atmosphere: dried acetonitrile under nitrogen flow
Geometry: three-electrode cell
Context: PMC-1
Measurement source: 6804 · Results/discussion · Figure 3a

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Initial reduction state where oxidation ceases	-0.7 +/- 0.1 e-	—	+/- 0.1	Text Rounded Reported	6804 · Results/discussion · Figure 3a
Reversible reduction half-wave potential in LiClO4Marked as a best value within this paper	E1/2red = -0.77 V vs Fc/Fc+	—	—	Text Exact Reported	6804 · Results/discussion · Figure 3a
Reduction peak potential in LiClO4	Epred = -0.88 V vs Fc/Fc+	—	—	Text Exact Reported	6804 · Results/discussion · Figure 3a

Solid-state cyclic voltammetry, n-Bu4NPF6 electrolyte

Voltammetry

PMC-1 bulk powder/crystals · Powder

PMC-1-modified glassy carbon electrode; 0.1 M n-Bu4NPF6 in CH3CN; scan rate 100 mV/s; Fc/Fc+ calibration.

Atmosphere: dried acetonitrile under nitrogen flow
Geometry: three-electrode cell
Context: PMC-1
Measurement source: 6804 · Results/discussion · Figure 3a, Figure S7

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Reduction peak potential in n-Bu4NPF6	Epred = -1.12 V vs Fc/Fc+	—	—	Text Exact Reported	6804 · Results/discussion · Figure 3a, Figure S7