Porosity — Porous Molecular Conductor: Electrochemical Fabrication of Through-Space Conduction Pathways among Linear Coordination Polymers

Measurement evidence

Porosity

Porous Molecular Conductor: Electrochemical Fabrication of Through-Space Conduction Pathways among Linear Coordination Polymers · Qu L., Iguchi H., Takaishi S. et al. · Journal of the American Chemical Society · 2019 · 6802-6806

1 measurement group · 1 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Ion-size-dependent solid-state CV used as porosity/selectivity probe

Voltammetry

PMC-1 bulk powder/crystals · Powder

Comparison of LiClO4 and n-Bu4NPF6 electrolytes during reduction of PMC-1.

Atmosphere: CH3CN; nitrogen flow for CV acquisition
Geometry: PMC-1-modified GC electrode
Context: PMC-1
Measurement source: 6804 · Results/discussion · Figure 3a

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Ion-size selectivity evidence for porosityMarked as a best value within this paper	Li+ ions can readily enter void space; bulky n-Bu4N+ ions are impeded	—	—	Qualitative Qualitative	6804 · Results/discussion · Figure 3a