Other — Porous Molecular Conductor: Electrochemical Fabrication of Through-Space Conduction Pathways among Linear Coordination Polymers

Measurement evidence

Other

Porous Molecular Conductor: Electrochemical Fabrication of Through-Space Conduction Pathways among Linear Coordination Polymers · Qu L., Iguchi H., Takaishi S. et al. · Journal of the American Chemical Society · 2019 · 6802-6806

2 measurement groups · 4 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Thermogravimetry

Thermogravimetric analysis

PMC-1 bulk powder/crystals · Powder

SHIMADZU DTG-60/60H; heating rate 5 deg C/min under nitrogen flow 0.1 L/min.

Atmosphere: nitrogen
Geometry: bulk solid
Context: PMC-1 thermal stability/desolvation
Measurement source: 6803 · Results/discussion · Figure S2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
PMC-1 TG plateau temperature	around 210 deg C	483.15 K	around	Text Approximate	6803 · Results/discussion · Figure S2

Thermogravimetry

Thermogravimetric analysis

PMC-1h pressed pellet · Pellet

TG trace of PMC-1h with scan rate 5 deg C/min; used to quantify adsorbed water.

Atmosphere: not specified in Figure S5 caption; general TG method under nitrogen flow
Geometry: bulk solid
Context: PMC-1h desolvated/hydrated derivative
Measurement source: S9-S10 · Calculation of amount of NO3- · Figure S5

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Nitrate stoichiometry x in PMC-1h/PMC-1 familyMarked as a best value within this paper	x = 1.3 +/- 0.1	—	+/- 0.1	Text Rounded Reported	6803 · Results/discussion · Table S2
Adsorbed water m from TG for x = 1.3	0.7 H2O molecules	—	—	Text Rounded Reported	S9 · Calculation of amount of NO3- · Figure S5
PMC-1h water-related weight loss up to 100 deg C	2% weight loss up to 100 deg C	—	—	Text Rounded Reported	S9 · Calculation of amount of NO3- · Figure S5