Porosity — Electrocatalytic Hydrogen Evolution from a Cobaloxime-Based Metal-Organic Framework Thin Film

Measurement evidence

Porosity

Electrocatalytic Hydrogen Evolution from a Cobaloxime-Based Metal-Organic Framework Thin Film · Roy S., Huang Z., Bhunia A. et al. · Journal of the American Chemical Society · 2019 · 15942-15950

1 measurement group · 5 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

N2 sorption, BET analysis, DFT pore-size fitting

Gas sorption and porosity Density functional theory

Activated or solvent-exchanged UU-100(Co) powder · Powder

Activated material measured at 77 K after dynamic vacuum activation; partially collapsed structure.

Temperature: 77
Atmosphere: N2
Context: activated pristine framework powder
Measurement source: 15944 · Synthesis and Characterization · Figure 2F-G; Figure S15

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BET surface areaMarked as a best value within this paper	902 +/- 15 m2 g-1	—	+/- 15 m2 g-1	Text Exact Reported	15944 · Synthesis and Characterization · Figure 2F; Figure S15
DFT pore-size distribution range	12-18 A	—	range 12-18 A	Text Range	15944 · Synthesis and Characterization · Figure 2G
Saturated N2 uptake	285 cm3 g-1	—	—	Text Exact Reported	15944 · Synthesis and Characterization · Figure 2F
Total pore volumeMarked as a best value within this paper	0.43 cm3 g-1	—	—	Text Exact Reported	15944 · Synthesis and Characterization · Figure 2F
Theoretical surface area	2867.9 m2 g-1	—	—	Text Exact Reported	15944 · Synthesis and Characterization