Spectroscopy

ICP-AES

Y/Eu-MOF crystalline catalyst · Single Crystal

Bulk metal content analysis for Y and Eu after acidic digestion.

Context: pristine mixed-metal framework
Measurement source: S3, S7 · General experimental information; Chemical characterization · Table S2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
expected Y to Eu ratio from formula	2.33	—	—	Calculated From Reported Exact Reported	3 · 2.2 Chemical Composition
europium content by ICP-AES	1268 mg/L	—	—	SI Table Exact Reported	S7 · 3. Chemical characterization of compounds · Table S2
europium concentration by ICP-AES	8.34 mM Eu3+	—	—	SI Table Exact Reported	S7 · 3. Chemical characterization of compounds · Table S2
Y to Eu ratio by ICP-AESMarked as a best value within this paper	2.25	—	—	Text Exact Reported	3 · 2.2 Chemical Composition
yttrium content by ICP-AES	1672 mg/L	—	—	SI Table Exact Reported	S7 · 3. Chemical characterization of compounds · Table S2
yttrium concentration by ICP-AES	18.8 mM Y3+	—	—	SI Table Exact Reported	S7 · 3. Chemical characterization of compounds · Table S2

Y/Eu-MOF crystalline catalyst · Single Crystal

Elemental analysis of Y/Eu-MOF on Elementar vario EL cube in CHN mode; table also reports O, Y, and Eu percentages.

Context: pristine mixed-metal framework
Measurement source: S3, S7 · General experimental information; Chemical characterization · Table S1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source

Y/Eu-MOF crystalline catalyst · Single Crystal

ATR spectra for ligand and Y/Eu-MOF collected over 400-4000 cm-1 on Nicolet 6700 FTIR with KBr pellets.

Context: pristine mixed-metal framework
Measurement source: S3, S14 · 7. FTIR analysis of Ligand and Catalyst · Figure S2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
N-H stretching peak	around 3617 cm-1	—	around	Text Approximate	S14 · 7. FTIR analysis of Ligand and Catalyst · Figure S2