Complete recipeSource: Both
Route 1: Solvothermal
7 · 3.2 Synthesis of Catalyst and General Procedures of Catalysis
Metal precursorsEu(NO3)3.5H2O (0.006 g, 0.0145 mmol); Y(NO3)3.6H2O (0.011 g, 0.0289 mmol)
Linker precursors3-amino-4-hydroxybenzoic acid (0.010 g, 0.0625 mmol)
SolventsDMF and distilled water
AdditivesEt3N (10 uL, 0.072 mmol)
Atmospherenot specified for MOF synthesis
Temperature100
Time2
Work-upMetal solution was added dropwise under continuous agitation to ligand solution; brown solution heated in screw-capped 6 mL vial to yield hexagonal single crystals.
Activationnot specified; formula retains coordinated water and 12 DMF molecules
Scalability contextSI provides a larger-scale variant with 0.2 g linker and 83 mg isolated product.
Show 6 structured reagent records
| Role | Reagent | Amount / concentration | Source |
|---|---|---|---|
| Linker | 3-amino-4-hydroxybenzoic acid | 0.010 g, 0.0625 mmol | 7 · 3.2 Synthesis of Catalyst and General Procedures of Catalysis |
| Solvent | DMF | 0.2 mL initially plus 0.2 mL added to metal solution | 7 · 3.2 Synthesis of Catalyst and General Procedures of Catalysis |
| Base | Et3N | 10 uL, 0.072 mmol | 7 · 3.2 Synthesis of Catalyst and General Procedures of Catalysis |
| Metal Source | Eu(NO3)3.5H2O | 0.006 g, 0.0145 mmol | 7 · 3.2 Synthesis of Catalyst and General Procedures of Catalysis |
| Metal Source | Y(NO3)3.6H2O | 0.011 g, 0.0289 mmol | 7 · 3.2 Synthesis of Catalyst and General Procedures of Catalysis |
| Solvent | distilled water | 0.8 mL initially plus 0.8 mL added to ligand solution | 7 · 3.2 Synthesis of Catalyst and General Procedures of Catalysis |