Electrochemistry Application — Anionic metal-organic framework modified separator boosting efficient Li-ion transport

7 measurement groups · 22 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

UIOSOL@PP separator · Thin Film

Asymmetric Cu|Li cells at 1 mA cm-2 with 1 mAh cm-2 plating capacity.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
CE PP by cycle 36	22% by the 36th cycle	—	—	Text Exact Reported	5 · Result and discussion · Fig. 5a
Average CE PP first 25 cycles	93% for first 25 cycles	—	—	Text Exact Reported	5 · Result and discussion · Fig. 5a
CE UIOSOL@PP over 100 cyclesMarked as a best value within this paper	about 95 during 100 cycles	—	about	Text Approximate	5 · Result and discussion · Fig. 5a

UIOSOL@PP separator · Thin Film

Coin cells with stainless steel working electrode and Li counter electrode; scan rate 1.0 mV s-1 between -0.2 and 4.3 V.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Peak stripping current density PP	0.49 mA cm-2 (calculated from 0.77 / 1.57)	—	—	Calculated From Reported Approximate	4 · Result and discussion · Fig. 3f
Peak stripping current density UIOSOL@PPMarked as a best value within this paper	0.77 mA cm-2	—	—	Text Exact Reported	4 · Result and discussion · Fig. 3f

UIOSOL@PP separator · Thin Film

LFP|Li cells cycled at 1C with PP, UIO@PP, UIOSOH@PP and UIOSOL@PP separators.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
LFP\|Li capacity with PP after 170 cycles	100 mAh g-1 after 170 cycles	—	—	Text Exact Reported	5 · Result and discussion · Fig. 6c
LFP\|Li initial capacity with PP at 1C	150 mAh g-1	—	—	Text Exact Reported	5 · Result and discussion · Fig. 6c
LFP\|Li capacity with UIO@PP after 135 cycles	153 mAh g-1 after 135 cycles	—	—	Text Exact Reported	5 · Result and discussion · Fig. S15
LFP\|Li CE with UIO@PP	CE drops to 98%	—	—	Text Exact Reported	5 · Result and discussion · Fig. S15
LFP\|Li capacity with UIOSOH@PP after 90 cycles	151 mAh g-1 after 90 cycles	—	—	Text Exact Reported	6 · Result and discussion · Fig. S15
LFP\|Li capacity with UIOSOL@PP after 640 cyclesMarked as a best value within this paper	155.2 mAh g-1 after 640 cycles	—	—	Text Exact Reported	6 · Result and discussion · Fig. 6c
Average CE with UIOSOL@PP after 640 cyclesMarked as a best value within this paper	99.5%	—	—	Text Exact Reported	6 · Result and discussion · Fig. 6c

UIOSOL@PP separator · Thin Film

LFP cathode and Li metal anode; rates stepped from 0.1C to 5C and back to 0.1C.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
LFP\|Li discharge capacity at 0.1C	similar discharge capacities of 160 mAh g-1	—	—	Text Rounded Reported	5 · Result and discussion · Fig. 6a,b
LFP\|Li discharge capacity at 5C with PP	100 mAh g-1	—	—	Text Exact Reported	5 · Result and discussion · Fig. 6a
LFP\|Li discharge capacity at 5C with UIOSOL@PPMarked as a best value within this paper	125 mAh g-1	—	—	Text Exact Reported	5 · Result and discussion · Fig. 6a
LFP\|Li capacity recovered at 0.1C with UIOSOL@PPMarked as a best value within this paper	161 mAh g-1	—	—	Text Exact Reported	5 · Result and discussion · Fig. 6a

UIOSOL@PP separator · Thin Film

Li|Li cells at 0.5 mA cm-2 with 1 mAh cm-2 areal capacity.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
PP Li\|Li voltage after 320 h	90 mV at 320 h	—	—	Text Exact Reported	5 · Result and discussion · Fig. 5b
UIOSOL@PP Li\|Li voltage plateauMarked as a best value within this paper	~12 mV for each charging-discharging cycle over 800 h	—	~	Text Approximate	5 · Result and discussion · Fig. 5b

UIOSOL@PP separator · Thin Film

Li-steel coin cell, scan speed 1 mV s-1 from initial voltage to 4.3 V; electrolyte EC/EMC/DMC 1:1:1 with 10% FEC.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Electrochemical stability window PP	4.3 V versus Li+/Li	—	—	Text Rounded Reported	3 · Result and discussion · Fig. 3a
Electrochemical stability window UIOSOL@PPMarked as a best value within this paper	up to 4.5 V versus Li+/Li	—	—	Text Rounded Reported	3 · Result and discussion · Fig. 3a

UIOSOL@PP separator · Thin Film

NCM523 cathode high loading 12 mg cm-2; 1C cycling for 50 cycles.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
NCM523\|Li capacity with PP after 50 cycles	113.7 mAh g-1 after 50 cycles under 1C	—	—	Text Exact Reported	6 · Result and discussion · Fig. S16
NCM523\|Li capacity with UIOSOL@PP after 50 cyclesMarked as a best value within this paper	122.3 mAh g-1 after 50 cycles under 1C	—	—	Text Exact Reported	6 · Result and discussion · Fig. S16