cMOF Evidence Base

Synthesis evidence

Anionic metal-organic framework modified separator boosting efficient Li-ion transport

Li J., Chen L., Wang F. et al. · Chemical Engineering Journal · 2023 · 138536

5 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Complete recipeSource: Main

Route 1: Hydrothermal

7 · Synthesis of UIO-66/UIO-SOLi Nanoparticles

Metal precursorsZrCl4 (433.5 mg)
Linker precursorsBDC (309 mg)
SolventsDMF (30 ml)
AdditivesHCOOH (7.13 ml)
Temperature150
Time24
Work-upCool to room temperature; centrifuge; wash three times with water and ethanol.
ActivationDried at 60 deg C overnight.
Show 4 structured reagent records
RoleReagentAmount / concentrationSource
Metal SourceZrCl4433.5 mg7 · Synthesis of UIO-66/UIO-SOLi Nanoparticles
LinkerBDC309 mg7 · Synthesis of UIO-66/UIO-SOLi Nanoparticles
AcidHCOOH7.13 ml7 · Synthesis of UIO-66/UIO-SOLi Nanoparticles
SolventDMF30 ml7 · Synthesis of UIO-66/UIO-SOLi Nanoparticles
Complete recipeSource: Main

Route 2: Drop Cast

7 · Fabrication of UIO@PP/UIOSOL@PP Separators

Metal precursorsUIO-66 particles (85 mg)
Linker precursorsUiO-66 framework linkers
Solventsethanol (2.5 ml)
AdditivesPAA binder (15 mg)
Temperature30
Time24
Substrate orientationPP separator sprayed with iwata atomising lance
Work-upSonicate for 1 h during stirring; spray homogeneous viscous solution on PP; dry at room temperature.
Scalability contextSpray coating with atomising lance; MOF:binder mass ratio 85:15.
Show 3 structured reagent records
RoleReagentAmount / concentrationSource
OtherUIO-66 particles85 mg7 · Fabrication of UIO@PP/UIOSOL@PP Separators
AdditivePAA15 mg7 · Fabrication of UIO@PP/UIOSOL@PP Separators
Solventethanol2.5 ml7 · Fabrication of UIO@PP/UIOSOL@PP Separators
Partial recipeSource: Main

Route 3: Hydrothermal

7 · Synthesis of UIO-66/UIO-SOLi Nanoparticles

Metal precursorsZrOCl2.8H2O (350 mg)
Linker precursorsBDC (90 mg); NaSO3-H2BDC (145 mg)
SolventsNot explicitly named in sentence; reagent list includes DMF, DMA and DMSO for MOF synthesis
AdditivesHCOOH (4.095 ml)
Temperature150
Time24
Work-upCollected by centrifugation, washed and dried.
ActivationDried; exact drying temperature/time for UIO-SOH not separated from subsequent UIO-SOLi route.
Show 4 structured reagent records
RoleReagentAmount / concentrationSource
Metal SourceZrOCl2.8H2O350 mg7 · Synthesis of UIO-66/UIO-SOLi Nanoparticles
LinkerBDC90 mg7 · Synthesis of UIO-66/UIO-SOLi Nanoparticles
LinkerNaSO3-H2BDC145 mg7 · Synthesis of UIO-66/UIO-SOLi Nanoparticles
AcidHCOOH4.095 ml7 · Synthesis of UIO-66/UIO-SOLi Nanoparticles
Partial recipeSource: Main

Route 4: Other

7 · Synthesis of UIO-66/UIO-SOLi Nanoparticles

Metal precursorsUIO-SOH powder
Linker precursorsBDC/BDC-NaSO3 linkers in UIO-SOH
SolventsDMSO
Additivestwo equivalents of LiAc
Temperature65
Time6
Work-upCentrifuge; wash with water and ethanol three times each.
ActivationDried at 60 deg C overnight.
Show 3 structured reagent records
RoleReagentAmount / concentrationSource
OtherUIO-SOH powderNot specified7 · Synthesis of UIO-66/UIO-SOLi Nanoparticles
AdditiveLiActwo equivalents7 · Synthesis of UIO-66/UIO-SOLi Nanoparticles
SolventDMSONot specified7 · Synthesis of UIO-66/UIO-SOLi Nanoparticles
Complete recipeSource: Main

Route 5: Drop Cast

7 · Fabrication of UIO@PP/UIOSOL@PP Separators

Metal precursorsUIO-SOLi particles (replacing UIO-66; mass inferred from same process as 85 mg)
Linker precursorsUIO-SOLi framework linkers
Solventsethanol (2.5 ml, inferred same process)
AdditivesPAA binder (15 mg, inferred same process)
Temperature30
Time24
Substrate orientationPP separator sprayed with iwata atomising lance
Work-upSonicate for 1 h during stirring; spray homogeneous viscous solution on PP; dry at room temperature.
Scalability contextThin MOF coating allowed high UIO-SOLi:binder ratio of 85:15.
Show 3 structured reagent records
RoleReagentAmount / concentrationSource
OtherUIO-SOLi particles85 mg inferred from same process7 · Fabrication of UIO@PP/UIOSOL@PP Separators
AdditivePAA15 mg inferred from same process7 · Fabrication of UIO@PP/UIOSOL@PP Separators
Solventethanol2.5 ml inferred from same process7 · Fabrication of UIO@PP/UIOSOL@PP Separators