Electrical Transport — Confinement of single polysilane chains in coordination nanospaces

4 measurement groups · 9 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

polycrystalline 1a-PMPrS in PMMA matrix on quartz for TRMC · Thin Film

355 nm Nd:YAG laser pulse, 1.0 x 10^16 photons cm-2, microwave frequency about 9.1 GHz, power 3 mW, room temperature.

Temperature: 298
Atmosphere: room-temperature measurement; atmosphere not specified
Geometry: polycrystalline composite film in PMMA matrix on quartz at microwave cavity electric-field maximum
Context: guest-loaded composite transport sample
Measurement source: p003-p006 · Time-Resolved Microwave Conductivity; Charge Carrier Mobility · Figure 6

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
1a-PMPrS charge-carrier local dislocation	Delta x = 0.88 nm	8.8e-10 m	—	Calculated From Reported Exact Reported	p006 · Charge Carrier Mobility of PMPrS in 1 · Equation 2
1a-PMPrS local hole mobilityMarked as a best value within this paper	mu = 3.0 x 10^-2 cm2 V-1 s-1	0.000003 m2 V-1 s-1	—	Text Exact Reported	p006 · Charge Carrier Mobility of PMPrS in 1 · Figure 6
1a-PMPrS approximate peak phi Sigma mu transient	approx. 1.8 x 10^-3 cm2 V-1 s-1 from Figure 6 initial peak	1.8e-7 m2 V-1 s-1	visual estimate	Figure Axis Approximate	p006 · Charge Carrier Mobility of PMPrS in 1 · Figure 6
reported PMPrS persistence length benchmark	q approximately 0.4 nm	4e-10 m	approximately	Text Approximate	p006 · Charge Carrier Mobility of PMPrS in 1

polycrystalline 1b-PMPrS in PMMA matrix on quartz for TRMC · Thin Film

355 nm Nd:YAG laser pulse, 1.0 x 10^16 photons cm-2, microwave frequency about 9.1 GHz, power 3 mW, room temperature.

Temperature: 298
Atmosphere: room-temperature measurement; atmosphere not specified
Geometry: polycrystalline composite film in PMMA matrix on quartz at microwave cavity electric-field maximum
Context: guest-loaded composite transport sample
Measurement source: p003-p006 · Time-Resolved Microwave Conductivity; Charge Carrier Mobility · Figure 6

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
1b-PMPrS charge-carrier local dislocation	Delta x = 1.53 nm	1.53e-9 m	—	Calculated From Reported Exact Reported	p006 · Charge Carrier Mobility of PMPrS in 1 · Equation 2
1b-PMPrS local hole mobility	mu = 1.5 x 10^-2 cm2 V-1 s-1	0.0000015 m2 V-1 s-1	—	Text Exact Reported	p006 · Charge Carrier Mobility of PMPrS in 1 · Figure 6
1b-PMPrS approximate peak phi Sigma mu transient	approx. 1.5 x 10^-3 cm2 V-1 s-1 from Figure 6 initial peak	1.5e-7 m2 V-1 s-1	visual estimate	Figure Axis Approximate	p006 · Charge Carrier Mobility of PMPrS in 1 · Figure 6

bulk PMPrS blended with PMMA/PDI for TRMC and TAS · Thin Film

355 nm excitation at 1.0 x 10^16 photons cm-2; PDI 10 wt percent used to estimate quantum efficiency by donor-acceptor system.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
bulk PMPrS local hole mobility	bulk PMPrS: 1.0 x 10^-3 cm2 V-1 s-1	1e-7 m2 V-1 s-1	—	Text Exact Reported	p006 · Charge Carrier Mobility of PMPrS in 1 · Figure S7

pristine host 1a powder · Powder

355 nm excitation at 1.0 x 10^16 photons cm-2 for pristine hosts 1a and 1b.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
host-only TRMC response	Host 1 did not give any transient photoconductivity signals.	—	—	Text Qualitative	p006 · Charge Carrier Mobility of PMPrS in 1 · Figure S8