Complete recipeSource: Main
Route 1: Other
p002 · Experimental Section - Introduction of PMPrS into 1
Metal precursorspreformed Al PCP host 1a
Linker precursorspreformed 2,6-naphthalenedicarboxylate PCP framework
Solventshexane
AdditivesPMPrS guest polymer
Atmospherereduced pressure/evacuation during drying and solvent removal
Temperature150 activation; 120 loading/solvent removal
Time5 activation; 12 loading/solvent removal
Work-upHost powder immersed in PMPrS hexane solution at room temperature; hexane completely removed by evacuation at 120 C for 12 h to obtain powdery composite.
ActivationCompound 1 (150 mg) dried by evacuation at 150 C for 5 h before immersion.
Scalability contextGeneral procedure used 150 mg host and 64 mg PMPrS in 1 mL hexane, yielding 211 mg composite.
Show 3 structured reagent records
| Role | Reagent | Amount / concentration | Source |
|---|---|---|---|
| Other | compound 1a host powder | 150 mg | p002 · Experimental Section - Introduction of PMPrS into 1 |
| Additive | PMPrS | 64 mg | p002 · Experimental Section - Introduction of PMPrS into 1 |
| Solvent | hexane | 1 mL | p002 · Experimental Section - Introduction of PMPrS into 1 |