Porosity — Confinement of single polysilane chains in coordination nanospaces

5 measurement groups · 5 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

1a-PMPrS powder composite, 30 wt percent PMPrS · Powder

Oxygen adsorption at 298 K for 1-PMPrS.

Temperature: 298
Atmosphere: O2
Context: guest-loaded composite; text does not specify separately 1a versus 1b
Measurement source: p007 · UV Stability of PMPrS in 1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
oxygen adsorption ratio for 1-PMPrS at 298 K	ratio of adsorbed oxygen to 1-PMPrS was <10^-5 wt %	—	<	Text Exact Reported	p007 · UV Stability of PMPrS in 1

pristine host 1a powder · Powder

N2 adsorption at 77 K on BELSORP-mini; sample treated under reduced pressure (<10^-2 Pa) at 373 K for 5 h before measurement.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
1a approximate N2 uptake near P/P0 = 0.95	about 460 mL(STP) g-1 at P/P0 near 0.95	—	—	Figure Axis Approximate	S3 · Supporting Information · Figure S2a

1a-PMPrS powder composite, 30 wt percent PMPrS · Powder

N2 adsorption at 77 K on BELSORP-mini; sample treated under reduced pressure (<10^-2 Pa) at 373 K for 5 h before measurement.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
1a-PMPrS approximate N2 uptake near P/P0 = 0.95	about 145 mL(STP) g-1 at P/P0 near 0.95	—	—	Figure Axis Approximate	S3 · Supporting Information · Figure S2a

pristine host 1b powder · Powder

N2 adsorption at 77 K on BELSORP-mini; sample treated under reduced pressure (<10^-2 Pa) at 373 K for 5 h before measurement.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
1b approximate N2 uptake near P/P0 = 0.95	about 450 mL(STP) g-1 at P/P0 near 0.95	—	—	Figure Axis Approximate	S3 · Supporting Information · Figure S2b

1b-PMPrS powder composite, 30 wt percent PMPrS · Powder

N2 adsorption at 77 K on BELSORP-mini; sample treated under reduced pressure (<10^-2 Pa) at 373 K for 5 h before measurement.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
1b-PMPrS approximate N2 uptake near P/P0 = 0.95	about 115 mL(STP) g-1 at P/P0 near 0.95	—	—	Figure Axis Approximate	S3 · Supporting Information · Figure S2b