Electrical Transport — Magnetic and electrical behaviors of the homo-and heterometallic 1d and 3d coordination polymers based on the partial decomposition of the [cr(C2o4)3]3− building block

3 measurement groups · 14 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Compound 1 yellow crystals / polycrystalline pressed pellet · Pellet

room temperature; frequency range 0.1 Hz to 1 MHz; pressed polycrystalline pellet between brass electrodes

Temperature: RT
Atmosphere: not specified
Geometry: pressed pellet, approximate thickness 0.4-0.6 mm, between brass electrodes
Context: pristine coordination polymer pellet
Measurement source: 5 · 2.5. Electrical Study

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Impedance spectroscopy frequency range	0.1 Hz to 1 MHz	—	—	Text Range	5 · 2.5. Electrical Study
Equivalent-circuit resistance R for compound 1	6.09×10^11 Ω	609000000000 ohm	—	SI Table Exact Reported	7 · Table S7 · Table S7
CPE A parameter for compound 1	4.07×10^-12 s^a Ω^-1	—	—	SI Table Exact Reported	7 · Table S7 · Table S7
CPE exponent a for compound 1	0.87	—	—	SI Table Exact Reported	7 · Table S7 · Table S7
Pressed pellet thickness range for impedance samples	0.4 to 0.6 mm	—	—	Text Range	5 · 2.5. Electrical Study
DC conductivity of compound 1 at room temperature	2.21×10^-12 (Ω cm)^-1	2.21e-12 S cm^-1	—	SI Table Exact Reported	7 · Table S7 · Table S7

Compound 2 green prismatic crystals / polycrystalline pressed pellet · Pellet

room temperature; frequency range 0.1 Hz to 1 MHz; pressed polycrystalline pellet between brass electrodes

Temperature: RT
Atmosphere: not specified
Geometry: pressed pellet, approximate thickness 0.4-0.6 mm, between brass electrodes
Context: pristine coordination polymer pellet
Measurement source: 15-16 · 3.5. Electrical Study of Compounds 1-3 · Figure 12

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Equivalent-circuit resistance R for compound 2	6.84×10^10 Ω	68400000000 ohm	—	SI Table Exact Reported	7 · Table S7 · Table S7
CPE A parameter for compound 2	2.94×10^-11 s^a Ω^-1	—	—	SI Table Exact Reported	7 · Table S7 · Table S7
CPE exponent a for compound 2	0.63	—	—	SI Table Exact Reported	7 · Table S7 · Table S7
DC conductivity of compound 2 at room temperatureMarked as a best value within this paper	1.33×10^-11 (Ω cm)^-1	1.33e-11 S cm^-1	—	SI Table Exact Reported	7 · Table S7 · Table S7

Compound 3 dark green prismatic crystals / polycrystalline pressed pellet · Pellet

room temperature; frequency range 0.1 Hz to 1 MHz; pressed polycrystalline pellet between brass electrodes

Temperature: RT
Atmosphere: not specified
Geometry: pressed pellet, approximate thickness 0.4-0.6 mm, between brass electrodes
Context: pristine coordination polymer pellet
Measurement source: 15-16 · 3.5. Electrical Study of Compounds 1-3 · Figure 12

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Equivalent-circuit resistance R for compound 3	3.89×10^11 Ω	389000000000 ohm	—	SI Table Exact Reported	7 · Table S7 · Table S7
CPE A parameter for compound 3	9.45×10^-12 s^a Ω^-1	—	—	SI Table Exact Reported	7 · Table S7 · Table S7
CPE exponent a for compound 3	0.74	—	—	SI Table Exact Reported	7 · Table S7 · Table S7
DC conductivity of compound 3 at room temperature	2.41×10^-12 (Ω cm)^-1	2.41e-12 S cm^-1	—	SI Table Exact Reported	7 · Table S7 · Table S7