Spectroscopy — Magnetic and electrical behaviors of the homo-and heterometallic 1d and 3d coordination polymers based on the partial decomposition of the [cr(C2o4)3]3− building block

Measurement evidence

Spectroscopy

Magnetic and electrical behaviors of the homo-and heterometallic 1d and 3d coordination polymers based on the partial decomposition of the [cr(C2o4)3]3− building block · Kanizaj L., Senjug P., Pajic D. et al. · Materials · 2020 · 1-20

3 measurement groups · 3 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

FTIR spectroscopy using KBr pellets, Bruker Alpha-T spectrometer

Compound 1 yellow crystals / polycrystalline pressed pellet · Pellet

4000-350 cm-1 range; compound 1 oxalate-group bands

Geometry
KBr pellet
Context
pristine coordination polymer
Measurement source
3 and 6 · 2.1. Materials and Methods; 3.2. Infrared Study · Table 2
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Compound 1 bis(bidentate) oxalate asymmetric CO stretch1673 cm^-1Table
Exact Reported
6 · 3.2. Infrared (IR) Spectroscopic Study · Table 2

FTIR spectroscopy using KBr pellets, Bruker Alpha-T spectrometer

Compound 2 green prismatic crystals / polycrystalline pressed pellet · Pellet

4000-350 cm-1 range; compound 2 oxalate-group bands

Geometry
KBr pellet
Context
pristine coordination polymer
Measurement source
3 and 6 · 2.1. Materials and Methods; 3.2. Infrared Study · Table 2
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Compound 2 bidentate oxalate asymmetric CO stretches1702, 1679, 1634 cm^-1Table
Exact Reported
6 · 3.2. Infrared (IR) Spectroscopic Study · Table 2

FTIR spectroscopy using KBr pellets, Bruker Alpha-T spectrometer

Compound 3 dark green prismatic crystals / polycrystalline pressed pellet · Pellet

4000-350 cm-1 range; compound 3 oxalate-group bands

Geometry
KBr pellet
Context
pristine coordination polymer
Measurement source
3 and 6 · 2.1. Materials and Methods; 3.2. Infrared Study · Table 2
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Compound 3 bis(bidentate) oxalate asymmetric CO stretch1664 cm^-1Table
Exact Reported
6 · 3.2. Infrared (IR) Spectroscopic Study · Table 2