Spectroscopy — Bimetal MOF nanosheets as efficient anode materials for lithium-ion batteries

Measurement evidence

Spectroscopy

Bimetal MOF nanosheets as efficient anode materials for lithium-ion batteries · Liu X., Du J., Wu Y. et al. · Ionics · 2025 · 10097-10109

3 measurement groups · 17 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Fourier transform infrared spectroscopy (FT-IR), PerkinElmer Frontier

CoxFe1-x-MOF powder/nanosheet series · Nanosheet

Functional group assignment for CoxFe1-x-MOFs.

Context
pristine powder series
Measurement source
p003 / article p.10099 · Results and discussion · Fig. 1b
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
FTIR asymmetric carboxylate stretcharound 1560 cm-1Text
Approximate
p003 / article p.10099 · Results and discussion · Fig. 1b
FTIR symmetric carboxylate stretcharound 1374 cm-1Text
Approximate
p003 / article p.10099 · Results and discussion · Fig. 1b
FTIR C-H benzene-ring vibration753 cm-1Text
Rounded Reported
p003 / article p.10099 · Results and discussion · Fig. 1b

Ex situ XPS after cycling / at different electrochemical states

Co1/2Fe1/2-MOF LIB anode electrode · Electrode

XPS spectra of Co1/2Fe1/2-MOF electrode before/after cycling and at discharge/charge states.

Geometry
electrode recovered from Li half-cell
Context
cycled MOF/carbon/binder electrode
Measurement source
p009-p010 / article pp.10105-10106 · Results and discussion · Fig. 8
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Co 2p primary peak after discharge779.8 eVText
Exact Reported
p009 / article p.10105 · Results and discussion · Fig. 8b
Co 2p primary peak after discharge790.2 eVText
Exact Reported
p009 / article p.10105 · Results and discussion · Fig. 8b
Fe 2p peak after discharge to 0.01 V707.7 eVText
Exact Reported
p010 / article p.10106 · Results and discussion · Fig. 8c
Fe 2p peak after discharge to 0.01 V709.8 eVText
Exact Reported
p010 / article p.10106 · Results and discussion · Fig. 8c
Fe 2p peak interval after discharge55.9 eVText
Exact Reported
p010 / article p.10106 · Results and discussion · Fig. 8c
C-O-Li peak in discharged state289.2 eVText
Exact Reported
p010 / article p.10106 · Results and discussion · Fig. 8d
O-Li bond signal after discharge528.2 eVText
Exact Reported
p010 / article p.10106 · Results and discussion · Fig. 8e

X-ray photoelectron spectroscopy (XPS), VGMulti lab 2000, Al Ka radiation

Co1/2Fe1/2-MOF powder · Nanosheet

Surface chemical states of pristine Co1/2Fe1/2-MOF powder.

Context
pristine target powder
Measurement source
p003-p004 / article pp.10099-10100 · Results and discussion · Fig. 2
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Co 2p3/2 binding-energy increase in Co1/2Fe1/2-MOFincreased by 0.4 eVText
Exact Reported
p010 / article p.10106 · Results and discussion · Fig. 2e-f
Fe 2p3/2 binding-energy decrease in Co1/2Fe1/2-MOFdecreased by 0.3 eVText
Exact Reported
p010 / article p.10106 · Results and discussion · Fig. 2e-f
Pristine Co1/2Fe1/2-MOF C 1s C=C peak284.2 eVText
Rounded Reported
p003 / article p.10099 · Results and discussion · Fig. 2b
Pristine Co1/2Fe1/2-MOF Co 2p3/2 peak~781.4 eVText
Approximate
p003 / article p.10099 · Results and discussion · Fig. 2f
Pristine Co1/2Fe1/2-MOF Fe 2p3/2 peak~712.1 eVText
Approximate
p003 / article p.10099 · Results and discussion · Fig. 2e
Pristine Co1/2Fe1/2-MOF N 1s C-N peak399.25 eVText
Exact Reported
p003 / article p.10099 · Results and discussion · Fig. 2d
Pristine Co1/2Fe1/2-MOF O 1s C=O peak530.91 eVText
Exact Reported
p003 / article p.10099 · Results and discussion · Fig. 2c