cMOF Evidence Base

Synthesis evidence

Bimetal MOF nanosheets as efficient anode materials for lithium-ion batteries

Liu X., Du J., Wu Y. et al. · Ionics · 2025 · 10097-10109

6 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Vague recipeSource: Main

Route 1: Solvothermal

p002 / article p.10098 · Materials synthesis and characterization

Metal precursorsCo and Fe salts varied to nominal Co:Fe = 1:3; exact amounts not stated
Linker precursorsNH2-BDC
SolventsDMF, ethanol, water
Additivestriethylamine (TEA)
Atmospherenot stated
Time8 h ultrasonic treatment inferred from typical Co1/2Fe1/2-MOF route; 12 h drying inferred
Work-upCentrifugation, methanol rinsing, vacuum drying inferred from typical route.
ActivationDried in a vacuum oven at 60 deg C for 12 h inferred from typical route.
Show 4 structured reagent records
RoleReagentAmount / concentrationSource
Metal SourceCo(NO3)2.6H2Onot stated for Co1/4Fe3/4-MOFp002 / article p.10098 · Materials synthesis and characterization
Metal SourceFeCl3.6H2Onot stated for Co1/4Fe3/4-MOFp002 / article p.10098 · Materials synthesis and characterization
LinkerNH2-BDCnot stated for Co1/4Fe3/4-MOFp002 / article p.10098 · Materials synthesis and characterization
Basetriethylamine (TEA)not stated for Co1/4Fe3/4-MOFp002 / article p.10098 · Materials synthesis and characterization
Vague recipeSource: Main

Route 2: Solvothermal

p002 / article p.10098 · Materials synthesis and characterization

Metal precursorsCo and Fe salts varied to nominal Co:Fe = 3:1; exact amounts not stated
Linker precursorsNH2-BDC
SolventsDMF, ethanol, water
Additivestriethylamine (TEA)
Atmospherenot stated
Time8 h ultrasonic treatment inferred from typical Co1/2Fe1/2-MOF route; 12 h drying inferred
Work-upCentrifugation, methanol rinsing, vacuum drying inferred from typical route.
ActivationDried in a vacuum oven at 60 deg C for 12 h inferred from typical route.
Show 4 structured reagent records
RoleReagentAmount / concentrationSource
Metal SourceCo(NO3)2.6H2Onot stated for Co3/4Fe1/4-MOFp002 / article p.10098 · Materials synthesis and characterization
Metal SourceFeCl3.6H2Onot stated for Co3/4Fe1/4-MOFp002 / article p.10098 · Materials synthesis and characterization
LinkerNH2-BDCnot stated for Co3/4Fe1/4-MOFp002 / article p.10098 · Materials synthesis and characterization
Basetriethylamine (TEA)not stated for Co3/4Fe1/4-MOFp002 / article p.10098 · Materials synthesis and characterization
Vague recipeSource: Main

Route 3: Solvothermal

p002 / article p.10098 · Materials synthesis and characterization

Metal precursorsCo salt, amount not stated for Co-MOF
Linker precursorsNH2-BDC
SolventsDMF, ethanol, water
Additivestriethylamine (TEA)
Atmospherenot stated
Time8 h ultrasonic treatment inferred from typical Co1/2Fe1/2-MOF route; 12 h drying inferred
Work-upCentrifugation, methanol rinsing, vacuum drying inferred from typical route.
ActivationDried in a vacuum oven at 60 deg C for 12 h inferred from typical route.
Show 4 structured reagent records
RoleReagentAmount / concentrationSource
Metal SourceCo(NO3)2.6H2Onot stated for Co-MOFp002 / article p.10098 · Materials synthesis and characterization
LinkerNH2-BDCnot stated for Co-MOFp002 / article p.10098 · Materials synthesis and characterization
SolventDMF/ethanol/waternot stated for Co-MOFp002 / article p.10098 · Materials synthesis and characterization
Basetriethylamine (TEA)not stated for Co-MOFp002 / article p.10098 · Materials synthesis and characterization
Partial recipeSource: Main

Route 4: Solvothermal

p002 / article p.10098 · Materials synthesis and characterization

Metal precursors0.225 mmol Co(NO3)2.6H2O; 0.225 mmol FeCl3.6H2O
Linker precursors0.6 mmol NH2-BDC
SolventsDMF, ethanol, deionized water
Additives1 mL triethylamine (TEA)
Atmospherenot stated
Time8 h ultrasonic treatment; 12 h drying
Work-upCentrifuged, rinsed three times with methanol.
ActivationDried in a vacuum oven at 60 deg C for 12 h.
Show 7 structured reagent records
RoleReagentAmount / concentrationSource
Metal SourceCo(NO3)2.6H2O0.225 mmolp002 / article p.10098 · Materials synthesis and characterization
Metal SourceFeCl3.6H2O0.225 mmolp002 / article p.10098 · Materials synthesis and characterization
LinkerNH2-BDC0.6 mmolp002 / article p.10098 · Materials synthesis and characterization
SolventN,N-dimethylformamide (DMF)13 mL in solution A and 13 mL in solution Bp002 / article p.10098 · Materials synthesis and characterization
Solventethanol1 mL in solution A and 1 mL in solution Bp002 / article p.10098 · Materials synthesis and characterization
Solventdeionized water1 mL in solution A and 1 mL in solution Bp002 / article p.10098 · Materials synthesis and characterization
Basetriethylamine (TEA)1 mLp002 / article p.10098 · Materials synthesis and characterization
Complete recipeSource: Main

Route 5: Drop Cast

p003 / article p.10099 · Cells fabrication and electrochemical measurements

SolventsN-methyl-2-pyrrolidone
AdditivesKetjen black; polyvinylidene fluoride
Atmosphereargon-filled glovebox for cell assembly
Temperature60
Time24
Substrate orientationcopper foil current collector
Work-upSlurry cast on copper foil and dried under vacuum; CR2032 half-cells aged overnight before testing.
Show 4 structured reagent records
RoleReagentAmount / concentrationSource
AdditiveKetjen black30 wt% of active:carbon:binder = 60:30:10p003 / article p.10099 · Cells fabrication and electrochemical measurements
Additivepolyvinylidene fluoride10 wt% of active:carbon:binder = 60:30:10p003 / article p.10099 · Cells fabrication and electrochemical measurements
SolventN-methyl-2-pyrrolidonenot statedp003 / article p.10099 · Cells fabrication and electrochemical measurements
ElectrolyteLiPF6 in EC/DEC1 M LiPF6; EC/DEC 1:1 v/vp003 / article p.10099 · Cells fabrication and electrochemical measurements
Vague recipeSource: Main

Route 6: Solvothermal

p002 / article p.10098 · Materials synthesis and characterization

Metal precursorsFe salt, amount not stated for Fe-MOF
Linker precursorsNH2-BDC
SolventsDMF, ethanol, water
Additivestriethylamine (TEA)
Atmospherenot stated
Time8 h ultrasonic treatment inferred from typical Co1/2Fe1/2-MOF route; 12 h drying inferred
Work-upCentrifugation, methanol rinsing, vacuum drying inferred from typical route.
ActivationDried in a vacuum oven at 60 deg C for 12 h inferred from typical route.
Show 4 structured reagent records
RoleReagentAmount / concentrationSource
Metal SourceFeCl3.6H2Onot stated for Fe-MOFp002 / article p.10098 · Materials synthesis and characterization
LinkerNH2-BDCnot stated for Fe-MOFp002 / article p.10098 · Materials synthesis and characterization
SolventDMF/ethanol/waternot stated for Fe-MOFp002 / article p.10098 · Materials synthesis and characterization
Basetriethylamine (TEA)not stated for Fe-MOFp002 / article p.10098 · Materials synthesis and characterization