Song S., Ma X., Zhang B. et al. · Journal of Energy Storage · 2022 · 103627
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
The E-NCT MOF//AC asymmetric supercapacitor delivers 29.34 Wh kg^-1 at 377.27 W kg^-1 and retains 73.6% capacitance after 10000 cycles.
Caveat: Device performance uses a composite electrode and activated carbon counter-electrode; mass-balancing equation is reported, but detailed electrode loading is not provided.
10 · 4. Conclusion · Linked to 3 structured results
The paper is relevant to conductive-MOF transport physics through EIS/electrochemical electron-transfer discussion, but it does not report direct electrical conductivity, carrier mobility, Hall, Seebeck or thermoelectric measurements.
3 · 2.4. Electrochemical measurements · Linked to 2 structured results
Ethanol synthesis gives sheet-like E-NCT MOF, which provides more electron-transport paths and ion-migration active sites than the lower-protonation solvent variants, producing the highest capacitance.
Caveat: Electrode capacitance data are measured on MOF/acetylene-black/PTFE composites on nickel foam, not on binder-free pristine powder.
1 · Abstract · Linked to 4 structured results
Increasing solvent protonation changes NCT MOF morphology from spherical/block-like particles toward thinner flakes/sheets by changing ligand solubility, metal coordination and nucleation rate.
Caveat: Mechanism is interpretive and based on morphology/XRD trends, not direct in situ nucleation measurements.
6 · 3.1. Structural and morphology characterization · Linked to 3 structured results
Mixed Ni and Co valence states provide redox-active sites and support fast Faradaic reactions, improving capacitance performance.
Caveat: XPS valence-state assignment is ex situ; direct electronic conductivity is not measured.
6 · 3.1. Structural and morphology characterization · Figure 5 · Linked to 6 structured results
The thiophene ligand's electron-rich planar semiconductor character is proposed to increase electrochemical activity and improve electron transport relative to the terephthalate comparison.
Caveat: The paper infers improved electron transport from electrochemical behaviour and EIS; no direct conductivity or mobility measurement is reported.
10 · 3.3. Electrochemical properties of the asymmetric supercapacitor · Linked to 4 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| E-NCT MOF//AC asymmetric supercapacitor | Not specifiedNi/Co MOF positive electrode; activated carbon negative electrode · 2,5-thiophene dicarboxylic acid in E-NCT MOF | 2D · CompositeTwo-electrode asymmetric supercapacitor assembled from E-NCT MOF and activated carbon. | 9 · 3.3. Electrochemical properties of the asymmetric supercapacitor · Figure 8 |
| Thienyl Ni/Co bimetallic MOF (NCT MOF) | Not specifiedNi and Co bimetal nodes from Ni(NO3)2.6H2O and Co(NO3)2.6H2O · 2,5-thiophene dicarboxylic acid / H2TDC as reported in title and discussion; chemicals section prints H2TDC as 2,5-furandicarboxylic acid | 2D · PristineNi-Co bimetal thienyl MOF; solvent controls morphology from spherical/block-like to sheet-like; Scheme 1 shows a structure constructed from CCDC No.1545260. | 2 · Introduction |
| Terephthalate-based Ni/Co bimetal MOF (PTA-NC MOF) | Not specifiedNi and Co bimetal nodes · terephthalic acid (PTA) | unknown · PristineTerephthalate-based Ni/Co bimetal MOF comparison sample; detailed XRD/IR/SEM/TEM characterisation is referenced in SI figures whose embedded content was not readable from the supplied SI text. | 3 · 2.2. Materials preparation |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| D-NCT MOF working electroderesearch_0414__mat__mat_nct_mof | Electrode · Pristine Control · Composite | D-NCT MOF mixed with acetylene black and PTFE in EtOH at 8:1.5:0.5 and coated on foamed nickel.foamed nickel | 3 · 2.4. Electrochemical measurements |
| D-NCT MOFresearch_0414__mat__mat_nct_mof | Powder · Pristine Control · Mixed Metal | DMF-solvothermal Ni/Co thienyl MOF powder; aprotic-solvent variant with spherical morphology. | 3 · 2.2. Materials preparation |
| E-NCT MOF//AC ASCresearch_0414__mat__mat_e_nct_ac_device | Electrode · Composite Sample · Composite | Asymmetric two-electrode supercapacitor using E-NCT MOF positive electrode and activated carbon negative electrode in 1 M KOH. | 9 · 3.3. Electrochemical properties of the asymmetric supercapacitor · Figure 9 |
| E-NCT MOF working electroderesearch_0414__mat__mat_nct_mof | Electrode · Target Sample · Composite | E-NCT MOF mixed with acetylene black and PTFE in EtOH at 8:1.5:0.5 and coated on foamed nickel.foamed nickel | 3 · 2.4. Electrochemical measurements |
| E-NCT MOFresearch_0414__mat__mat_nct_mof | Nanosheet · Target Sample · Mixed Metal | EtOH-solvothermal Ni/Co thienyl MOF powder; high-protonation solvent variant with two-dimensional sheet-like morphology.sheet-like structure in the range of 1 um to 5 um | 4 · 3.1. Structural and morphology characterization · Figure 2c,f,i |
| M-NCT MOF working electroderesearch_0414__mat__mat_nct_mof | Electrode · Pristine Control · Composite | M-NCT MOF mixed with acetylene black and PTFE in EtOH at 8:1.5:0.5 and coated on foamed nickel.foamed nickel | 3 · 2.4. Electrochemical measurements |
| M-NCT MOFresearch_0414__mat__mat_nct_mof | Powder · Pristine Control · Mixed Metal | MeOH-solvothermal Ni/Co thienyl MOF powder; low-protonation solvent variant with block-like/irregular spherical-flake morphology. | 3 · 2.2. Materials preparation |
| PTA-NC MOF working electroderesearch_0414__mat__mat_pta_nc_mof | Electrode · Pristine Control · Composite | PTA-NC MOF mixed with acetylene black and PTFE in EtOH at 8:1.5:0.5 and coated on foamed nickel.foamed nickel | 3 · 2.4. Electrochemical measurements |
| PTA-NC MOFresearch_0414__mat__mat_pta_nc_mof | Powder · Pristine Control · Mixed Metal | Terephthalate-based Ni/Co bimetal MOF prepared as ligand comparison sample. | 3 · 2.2. Materials preparation |