Spectroscopy — Copper-Metal Organic Frameworks Electrodeposited on Carbon Paper as an Enhanced Cathode for the Hydrogen Evolution Reaction

6 measurement groups · 7 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

HKUST-1 ED after 0.5 M H2SO4 soaking · Electrode

HKUST-1 ED soaked in 0.5 M H2SO4 for 2 h, then checked by SEM and Raman spectroscopy.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Raman bands after acid soaking	1610, 1005, 827, 745, 1463, 190, 450, 610 and 980 cm^-1	—	—	Text Exact Reported	SI p007 · Stability discussion · Figure S7c
Morphology after acid soaking	same octahedral structure on carbon paper after 0.5 M H2SO4 for 2 h	—	—	Text Qualitative	SI p007 · Stability discussion · Figure S7a,b

HKUST-1 ED on carbon paper · Electrode

FTIR spectrum of HKUST-1 ED.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
FTIR labelled peaks	1644, 1447, 1373, 730 and 490 cm^-1 labelled in Figure S4	—	—	Figure Axis Rounded Reported	SI p005 · Figure S4 · Figure S4

HKUST-1 ED on carbon paper · Electrode

Raman spectra of HKUST-1 ED compared with HKUST-1 HT.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Raman structure comparison	similar Raman patterns between HKUST-1 HT and ED indicated the same crystal structure	—	—	Text Qualitative	4508 · Results · Figure 2b

HKUST-1 HT powder/crystals · Powder

Horiba HR Evolution, 633 nm laser excitation, 100-1800 cm^-1 sweep.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source

HKUST-1 ED on carbon paper · Electrode

XPS around 930-950 eV using ESCALAB 250Xi with monochromatic Al Kalpha source.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Cu2+ Cu 2p3/2 peak	935.0 eV	—	—	Text Exact Reported	SI p004 · XPS discussion · Figure S3b
Small Cu-related peak in HKUST-1 ED	933.3 eV	—	—	Text Exact Reported	SI p004 · XPS discussion · Figure S3b

HKUST-1 HT powder/crystals · Powder

XPS around 930-950 eV using ESCALAB 250Xi with monochromatic Al Kalpha source.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Cu2+ Cu 2p3/2 peak	935.0 eV	—	—	Text Exact Reported	SI p004 · XPS discussion · Figure S3a