Diffraction Structure — MOF-Assimilated High-Sensitive Organic Field-Effect Transistors for Rapid Detection of a Chemical Warfare Agent

3 measurement groups · 16 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

as-synthesised CPO-27-Ni powder/crystals · Powder

PXRD of as-synthesised CPO-27-Ni and CPO-27-Ni after rigorous use/exposure for 2 years in ambient atmosphere.

Temperature: 298.15
Atmosphere: ambient, 45% RH
Geometry: powder
Context: pristine CPO-27-Ni MOF
Measurement source: SI p.S2-S3 · Powder x-ray diffraction pattern of CPO-27-Ni · Figure S2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
CPO-27-Ni ageing time before PXRD check	2 years	—	—	Text Exact Reported	SI p.S2-S3 · Powder x-ray diffraction pattern of CPO-27-Ni · Figure S2
ambient ageing relative humidity for CPO-27-Ni PXRD check	45% RH	—	—	Text Exact Reported	SI p.S2-S3 · Powder x-ray diffraction pattern of CPO-27-Ni · Figure S2
ambient ageing temperature for CPO-27-Ni PXRD check	25 deg C	298.15 K	—	Text Exact Reported	SI p.S2-S3 · Powder x-ray diffraction pattern of CPO-27-Ni · Figure S2
CPO-27-Ni PXRD stability after ageingMarked as a best value within this paper	crystallinity retained without degradation	—	—	Text Qualitative	SI p.S2-S3 · Powder x-ray diffraction pattern of CPO-27-Ni · Figure S2

as-synthesised CPO-27-Ni powder/crystals · Powder

Powder XRD collected at ambient temperature with scan speed 1 deg/min, step size 0.02 deg in 2theta, 2theta range 5-40 deg.

Atmosphere: ambient
Context: pristine CPO-27-Ni MOF powder
Measurement source: p003 / article p.30582 · Results and Discussion · Figure 1a-c; Figure S2 referenced

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
CPO-27-Ni a lattice parameter	a = 25.86 A	—	—	Text Exact Reported	p002 / article p.30581 · Introduction
CPO-27-Ni b lattice parameter	b = 25.86 A	—	—	Text Exact Reported	p002 / article p.30581 · Introduction
CPO-27-Ni c lattice parameter	c = 6.71 A	—	—	Text Exact Reported	p002 / article p.30581 · Introduction
Microporous 1D hexagonal channel diameter	12 A	—	—	Text Rounded Reported	p002 / article p.30581 · Introduction
CPO-27-Ni powder XRD (110) peak	2theta = 6.83 deg, (110)	—	—	Text Exact Reported	p003 / article p.30582 · Results and Discussion · Figure S2 referenced
CPO-27-Ni powder XRD (300) peak	2theta = 11.80 deg, (300)	—	—	Text Exact Reported	p003 / article p.30582 · Results and Discussion · Figure S2 referenced

CPO-27-Ni/pentacene bilayer OFET, 3000 rpm MOF coating · Thin Film

Thin-film XRD under ambient conditions, 2theta 4-20 deg at 2 deg/min, comparing pristine pentacene and CPO-27-Ni spin-coated bilayer films.

Atmosphere: ambient
Geometry: pentacene and CPO-27-Ni/pentacene films on h-BTNC dielectric
Context: composite bilayer series compared with pristine pentacene
Measurement source: p004 / article p.30583 · Results and Discussion · Figure 4

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
pentacene bulk phase first-order peak	2theta = 6.15 deg for (001)	—	—	Text Exact Reported	p004 / article p.30583 · Results and Discussion · Figure 4a,b
pentacene bulk phase interlayer spacing	14.35 A for (001)	—	—	Text Exact Reported	p004 / article p.30583 · Results and Discussion · Figure 4d
pentacene bulk phase molecular tilt angle	12.45 deg	—	—	Text Exact Reported	p005 / article p.30584 · Results and Discussion · Figure 4g
pentacene thin-film phase first-order peak	2theta = 5.71 deg for (001')	—	—	Text Exact Reported	p004 / article p.30583 · Results and Discussion · Figure 4a,b
pentacene thin-film phase interlayer spacing	15.45 A for (001') planes	—	—	Text Exact Reported	p004 / article p.30583 · Results and Discussion · Figure 4d
pentacene thin-film phase molecular tilt angle	24.13 deg	—	—	Text Exact Reported	p005 / article p.30584 · Results and Discussion · Figure 4g