cMOF Evidence Base
Sensing Application — MOF-Assimilated High-Sensitive Organic Field-Effect Transistors for Rapid Detection of a Chemical Warfare Agent

Measurement evidence

Sensing Application

MOF-Assimilated High-Sensitive Organic Field-Effect Transistors for Rapid Detection of a Chemical Warfare Agent · Mallik S., Chand Pal S., Acharyya S. et al. · ACS Applied Materials and Interfaces · 2023 · 30580-30590

4 measurement groups · 21 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

OFET DES vapour sensing

Field-effect transistor measurements

CPO-27-Ni/pentacene bilayer OFET, 3000 rpm MOF coating · Thin Film

DES vapour generated by injecting DES liquid into a sealed 200 uL chamber; device biased at Vg = Vd = -3 V under 25 deg C and RH about 45%; concentrations 104, 72, 51, 31, and 10 ppm.

Temperature
298
Atmosphere
ambient air, RH about 45%, DES vapour
Geometry
bottom-gate top-contact CPO-27-Ni/pentacene bilayer OFET
Context
composite bilayer selected at 3000 rpm
Measurement source
p006 / article p.30585 · Results and Discussion · Figure 6a-c
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
lowest measured DES concentrationMarked as a best value within this paper10 ppm——Text
Exact Reported		p007 / article p.30586 · Results and Discussion · Figure 6a,b
normalised drain current after 104 ppm DES exposureId(t)/Id(0) decreases to about 0.82 from Figure 6a——Figure Axis
Approximate		p007 / article p.30586 · Results and Discussion · Figure 6a
DES sensitivity at 104 ppmMarked as a best value within this paperabout 16.2% from Figure 6d——Figure Axis
Approximate		p007 / article p.30586 · Results and Discussion · Figure 6d
DES sensitivity at 10 ppmgreater than 4%——Text
Approximate		p008 / article p.30587 · Results and Discussion · Figure 6b
DES sensitivity at 31 ppmabout 5.0% from Figure 6d——Figure Axis
Approximate		p007 / article p.30586 · Results and Discussion · Figure 6d
DES sensitivity at 51 ppmabout 5.5% from Figure 6d——Figure Axis
Approximate		p007 / article p.30586 · Results and Discussion · Figure 6d
DES sensitivity at 72 ppmabout 8.3% from Figure 6d——Figure Axis
Approximate		p007 / article p.30586 · Results and Discussion · Figure 6d
response time at 10 ppm DESMarked as a best value within this paper31.33 (+/-1.52) s—+/-1.52 sText
Exact Reported		p008 / article p.30587 · Results and Discussion · Figure 6c
drain voltage during sensingVd = -3 V——Text
Exact Reported		p006 / article p.30585 · Results and Discussion
gate voltage during sensingVg = -3 V——Text
Exact Reported		p006 / article p.30585 · Results and Discussion
sensing chamber volumearound 200 uL0.2 mL—Text
Approximate		p006 / article p.30585 · Results and Discussion
relative humidity during sensingRH about 45%——Text
Approximate		p006 / article p.30585 · Results and Discussion
sensing temperature25 deg C298.15 K—Text
Exact Reported		p006 / article p.30585 · Results and Discussion
DES sensitivity power-law exponent3.58 (+/-0.48)—+/-0.48Text
Exact Reported		p007 / article p.30586 · Results and Discussion · Figure 6b

Selectivity test against DES, DPGME, nitrobenzene, and toluene

CPO-27-Ni/pentacene bilayer OFET, 3000 rpm MOF coating · Thin Film

OFET exposed to DES, di(propylene glycol) monomethyl ether, toluene, and nitrobenzene at 104, 72, 51, 31, and 10 ppm.

Temperature
298
Atmosphere
ambient vapour in sealed chamber
Geometry
bottom-gate top-contact CPO-27-Ni/pentacene bilayer OFET
Context
composite bilayer selected at 3000 rpm
Measurement source
p007 / article p.30586 · Results and Discussion · Figure 6d-f
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
DPGME sensitivity at 104 ppmabout 6.0% from Figure 6d——Figure Axis
Approximate		p007 / article p.30586 · Results and Discussion · Figure 6d
nitrobenzene sensitivity at 104 ppmabout 4.6% from Figure 6d——Figure Axis
Approximate		p007 / article p.30586 · Results and Discussion · Figure 6d
toluene sensitivity at 104 ppmabout 4.2% from Figure 6d——Figure Axis
Approximate		p007 / article p.30586 · Results and Discussion · Figure 6d

SI comparison table for pristine pentacene sulfur mustard simulant detection

pristine pentacene-based OFET · Thin Film

Table S1 this-work row for pristine pentacene OFET detection of BCES/sulfur mustard vapour simulant at 25 C.

Temperature
298.15
Atmosphere
ambient
Geometry
OFET based
Context
pristine pentacene control device
Measurement source
SI p.S7 · Table S1 · Table S1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
SI Table S1 pristine pentacene detection limitUp to 10 ppm——SI Table
Exact Reported		SI p.S7 · Table S1 · Table S1
SI Table S1 pristine pentacene sensitivitySensitivity ~2%——SI Table
Approximate		SI p.S7 · Table S1 · Table S1

SI comparison table for sulfur mustard simulant detection

CPO-27-Ni/pentacene bilayer OFET, 3000 rpm MOF coating · Thin Film

Table S1 this-work row for CPO-27-Ni/pentacene bilayer OFET detection of BCES/sulfur mustard vapour simulant at room temperature.

Temperature
298.15
Atmosphere
ambient
Geometry
OFET based
Context
CPO-27-Ni/pentacene bilayer device
Measurement source
SI p.S7 · Table S1 · Table S1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
SI Table S1 bilayer detection limitMarked as a best value within this paperBelow 10 ppm——SI Table
Approximate		SI p.S7 · Table S1 · Table S1
SI Table S1 bilayer sensitivityMarked as a best value within this papermore than 4%——SI Table
Approximate		SI p.S7 · Table S1 · Table S1