Electrical Transport — MOF-Assimilated High-Sensitive Organic Field-Effect Transistors for Rapid Detection of a Chemical Warfare Agent

Measurement evidence

Electrical Transport

MOF-Assimilated High-Sensitive Organic Field-Effect Transistors for Rapid Detection of a Chemical Warfare Agent · Mallik S., Chand Pal S., Acharyya S. et al. · ACS Applied Materials and Interfaces · 2023 · 30580-30590

6 measurement groups · 17 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

OFET transfer characteristics

CPO-27-Ni/pentacene bilayer OFET, 3000 rpm MOF coating · Thin Film

Transfer curve of CPO-27-Ni MOF layer coated at 3000 rpm over pentacene; mobility calculated from lower slope to avoid overestimation.

Atmosphere
ambient
Geometry
bottom-gate top-contact bilayer OFET
Context
composite bilayer
Measurement source
p006 / article p.30585 · Results and Discussion · Figure 5a
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
approximate maximum drain current at Vg about -3 Vabout 950 nA from Figure 5a0.95 uAFigure Axis
Approximate
p006 / article p.30585 · Results and Discussion · Figure 5a
threshold/operation voltage for bilayer OFEToperates below -0.5 VText
Approximate
p006 / article p.30585 · Results and Discussion · Figure 5a

Bias-stress stability under fixed Vg and Vd

CPO-27-Ni/pentacene bilayer OFET, 3000 rpm MOF coating · Thin Film

Bilayer OFET with MOF coated at 3000 rpm measured under continuous fixed bias for 30 min with Vg = Vd = -3 V.

Atmosphere
ambient
Geometry
BGTC OFET
Context
composite bilayer sensing device
Measurement source
SI p.S5 · Bias stress stability of OFET · Figure S5
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
bias-stress measurement duration30 min1800 sText
Exact Reported
SI p.S5 · Bias stress stability of OFET · Figure S5
final normalised drain current after 30 min bias stressabout 0.88 Id(t)/Id(0) from Figure S5Figure Axis
Approximate
SI p.S5 · Bias stress stability of OFET · Figure S5
peak normalised drain current under bias stressabout 1.4 Id(t)/Id(0) from Figure S5Figure Axis
Approximate
SI p.S5 · Bias stress stability of OFET · Figure S5

Long-term OFET transfer and mobility stability

CPO-27-Ni/pentacene bilayer OFET, 3000 rpm MOF coating · Thin Film

Transfer characteristics measured over 65 days under ambient atmosphere at room temperature; mobility extracted from transfer curves.

Temperature
298.15
Atmosphere
ambient
Geometry
BGTC OFET
Context
composite bilayer device stored/aged under ambient atmosphere for stability test
Measurement source
SI p.S5-S6 · Long term stability of the OFET · Figure S6
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
65-day carrier mobility from Figure S6babout 0.007 cm2/V/s at 65 days from Figure S6bFigure Axis
Approximate
SI p.S6 · Long term stability of the OFET · Figure S6b
long-term stability measurement duration65 daysText
Exact Reported
SI p.S5-S6 · Long term stability of the OFET · Figure S6
initial carrier mobility from Figure S6babout 0.026 cm2/V/s at day 0 from Figure S6bFigure Axis
Approximate
SI p.S6 · Long term stability of the OFET · Figure S6b
reported mobility reduction over 65 daysabout 20% reduction in 65 daysText
Approximate
SI p.S5-S6 · Long term stability of the OFET · Figure S6

Carrier mobility extraction from OFET transfer curves

CPO-27-Ni/pentacene bilayer OFET, 3000 rpm MOF coating · Thin Film

Carrier mobility compared for CPO-27-Ni/pentacene bilayer devices spin-coated at 2000, 3000, 4000, and 5000 rpm.

Atmosphere
ambient
Geometry
bottom-gate top-contact bilayer OFETs
Context
composite bilayer rpm series
Measurement source
p006 / article p.30585 · Results and Discussion · Figure 5c
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
bilayer OFET mobility at 2000 rpmabout 0.008 cm2/V/s from Figure 5cFigure Axis
Approximate
p006 / article p.30585 · Results and Discussion · Figure 5c
bilayer OFET mobility at 3000 rpmMarked as a best value within this paperabout 0.022 cm2/V/s from Figure 5cFigure Axis
Approximate
p006 / article p.30585 · Results and Discussion · Figure 5c
bilayer OFET mobility at 4000 rpmabout 0.018 cm2/V/s from Figure 5cFigure Axis
Approximate
p006 / article p.30585 · Results and Discussion · Figure 5c
bilayer OFET mobility at 5000 rpmabout 0.006 cm2/V/s from Figure 5cFigure Axis
Approximate
p006 / article p.30585 · Results and Discussion · Figure 5c

OFET transfer curves for SI rpm series

CPO-27-Ni/pentacene bilayer OFET, 2000 rpm MOF coating · Thin Film

Top-contact bottom-gate bilayer OFETs composed of CPO-27-Ni layer with 2000, 4000 and 5000 rpm coatings and pentacene.

Atmosphere
ambient
Geometry
BGTC OFET
Context
composite bilayer devices; complements main Figure 5c mobility extraction
Measurement source
SI p.S3-S4 · Electrical characterization · Figure S3
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
SI bilayer transfer-curve shapeall tested bilayer transfer curves possess a dual slopeText
Qualitative
SI p.S3 · Electrical characterization · Figure S3

OFET transfer characteristics

pristine pentacene-based OFET · Thin Film

Electrical characterisation using two Keithley 2450 instruments in a custom probe station under ambient conditions.

Atmosphere
ambient
Geometry
bottom-gate top-contact OFET
Context
pristine pentacene control
Measurement source
p006 / article p.30585 · Results and Discussion · Figure 5b
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
pure pentacene sensing responsepoor sensitivity toward 10 ppm DES / sulfur-based analytesText
Qualitative
p008 / article p.30587 · Results and Discussion
approximate maximum drain current at Vg about -3 Vabout 3000 nA from Figure 5b3 uAFigure Axis
Approximate
p006 / article p.30585 · Results and Discussion · Figure 5b
threshold voltage for pristine pentacene OFET-1.25 VText
Exact Reported
p006 / article p.30585 · Results and Discussion · Figure 5b