cMOF Evidence Base
Other — Metal-organic framework-mediated synthesis of LiNi0.5Mn1.5O4: Tuning the Mn3+ content and electrochemical performance by organic ligands

Measurement evidence

Other

Metal-organic framework-mediated synthesis of LiNi0.5Mn1.5O4: Tuning the Mn3+ content and electrochemical performance by organic ligands · Yin C., Bao Z., Tan H. et al. · Chemical Engineering Journal · 2019 · 408-419

7 measurement groups · 20 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

XRD, FTIR, SEM, TEM/EDS, TGA, ICP, XPS, Raman, BET

Infrared spectroscopyRaman spectroscopyX-ray photoelectron spectroscopyX-ray diffraction and scatteringScanning electron microscopyTransmission electron microscopyElemental microanalysis and mappingBulk elemental and compositional analysisGas sorption and porosityThermogravimetric analysis

PTCDA-LNMO powder · Powder

Characterisation instrument details reported for all Ni-Mn-MOF and LNMO samples.

Atmosphere
air flow 10 mL min-1 for TGA; N2 at 77 K for BET
Geometry
powder characterisation
Context
all precursor MOF and derived LNMO powders
Measurement source
2 · 2.2 Materials characterization
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
TGA heating rate10——Text
Exact Reported		2 · 2.2 Materials characterization
TGA air flow10——Text
Exact Reported		2 · 2.2 Materials characterization
Raman excitation wavelength633——Text
Exact Reported		2 · 2.2 Materials characterization
XRD scan range low angle10——Text
Exact Reported		2 · 2.2 Materials characterization
XRD scan range high angle80——Text
Exact Reported		2 · 2.2 Materials characterization
XRD scan rate5——Text
Exact Reported		2 · 2.2 Materials characterization
SI ligand structure panelsix ligand molecular structures shown——Qualitative
Qualitative		4 · Appendix A. Supporting Information · Fig. S5

thermogravimetric analysis / differential thermal analysis (TG/DTA)

Calorimetry and thermal analysisThermogravimetric analysis

BCA-Ni-Mn-MOFs · Powder

Air flow 10 mL min-1, heating rate 10 C min-1; SI Fig. S8 precursor TG/DTA curve.

Atmosphere
air
Context
MOF-derived calcination precursor
Measurement source
2 · 2.2 Materials characterization · method text
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
first weight lossDelta W1=6%——Figure Axis
Rounded Reported		6 · Appendix A. Supporting Information · Fig. S8
second weight lossDelta W2=56%——Figure Axis
Rounded Reported		6 · Appendix A. Supporting Information · Fig. S8

thermogravimetric analysis / differential thermal analysis (TG/DTA)

Calorimetry and thermal analysisThermogravimetric analysis

DTA-Ni-Mn-MOFs · Powder

Air flow 10 mL min-1, heating rate 10 C min-1; SI Fig. S8 precursor TG/DTA curve.

Atmosphere
air
Context
MOF-derived calcination precursor
Measurement source
2 · 2.2 Materials characterization · method text
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
first weight lossDelta W1=8%——Figure Axis
Rounded Reported		6 · Appendix A. Supporting Information · Fig. S8
second weight lossDelta W2=37%——Figure Axis
Rounded Reported		6 · Appendix A. Supporting Information · Fig. S8

thermogravimetric analysis / differential thermal analysis (TG/DTA)

Calorimetry and thermal analysisThermogravimetric analysis

OBA-Ni-Mn-MOFs · Powder

Air flow 10 mL min-1, heating rate 10 C min-1; SI Fig. S8 precursor TG/DTA curve.

Atmosphere
air
Context
MOF-derived calcination precursor
Measurement source
2 · 2.2 Materials characterization · method text
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
first weight lossDelta W1=9%——Figure Axis
Rounded Reported		6 · Appendix A. Supporting Information · Fig. S8
second weight lossDelta W2=67%——Figure Axis
Rounded Reported		6 · Appendix A. Supporting Information · Fig. S8

thermogravimetric analysis / differential thermal analysis (TG/DTA)

Calorimetry and thermal analysisThermogravimetric analysis

PTA-Ni-Mn-MOFs · Powder

Air flow 10 mL min-1, heating rate 10 C min-1; SI Fig. S8 precursor TG/DTA curve.

Atmosphere
air
Context
MOF-derived calcination precursor
Measurement source
2 · 2.2 Materials characterization · method text
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
first weight lossDelta W1=8%——Figure Axis
Rounded Reported		6 · Appendix A. Supporting Information · Fig. S8
second weight lossDelta W2=59%——Figure Axis
Rounded Reported		6 · Appendix A. Supporting Information · Fig. S8

thermogravimetric analysis / differential thermal analysis (TG/DTA)

Calorimetry and thermal analysisThermogravimetric analysis

PTCDA-Ni-Mn-MOFs · Powder

Air flow 10 mL min-1, heating rate 10 C min-1; SI Fig. S8 precursor TG/DTA curve.

Atmosphere
air
Context
MOF-derived calcination precursor
Measurement source
2 · 2.2 Materials characterization · method text
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
first weight lossDelta W1=15%——Figure Axis
Rounded Reported		6 · Appendix A. Supporting Information · Fig. S8
second weight lossDelta W2=56%——Figure Axis
Rounded Reported		6 · Appendix A. Supporting Information · Fig. S8

thermogravimetric analysis / differential thermal analysis (TG/DTA)

Calorimetry and thermal analysisThermogravimetric analysis

TCA-Ni-Mn-MOFs · Powder

Air flow 10 mL min-1, heating rate 10 C min-1; SI Fig. S8 precursor TG/DTA curve.

Atmosphere
air
Context
MOF-derived calcination precursor
Measurement source
2 · 2.2 Materials characterization · method text
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
first weight lossDelta W1=13%——Figure Axis
Rounded Reported		6 · Appendix A. Supporting Information · Fig. S8
second weight lossDelta W2=8%——Figure Axis
Rounded Reported		6 · Appendix A. Supporting Information · Fig. S8
third weight lossDelta W3=39%——Figure Axis
Rounded Reported		6 · Appendix A. Supporting Information · Fig. S8