Porosity — Metal-organic framework-mediated synthesis of LiNi0.5Mn1.5O4: Tuning the Mn3+ content and electrochemical performance by organic ligands

12 measurement groups · 48 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

N2 adsorption/desorption isotherm; BET surface area; pore-size distribution

Gas sorption and porosity

BCA-Ni-Mn-MOFs · Powder

Supporting Information adsorption-desorption isotherm for prepared Ni-Mn-MOF precursor

Temperature: 77
Atmosphere: N2
Context: pristine mixed-metal MOF precursor
Measurement source: 5 · Appendix A. Supporting Information · Fig. S7

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BET surface areaMarked as a best value within this paper	871.3	—	—	Figure Axis Rounded Reported	5 · Appendix A. Supporting Information · Fig. S7e
pore size	14.29	—	—	Figure Axis Rounded Reported	5 · Appendix A. Supporting Information · Fig. S7e
pore volume	1.245	—	—	Figure Axis Rounded Reported	5 · Appendix A. Supporting Information · Fig. S7e

N2 adsorption/desorption; BET; BJH pore volume; tap density

Gas sorption and porosity

BCA-LNMO powder · Powder

BET measured with ASAP 2020 at liquid nitrogen temperature (77 K); isotherms classified as type IV with narrow mesopores 5-10 nm.

Temperature: 77
Atmosphere: N2
Geometry: powder sorption
Context: derived LNMO powder
Measurement source: 6-7 · 2.2 Materials characterization / 3. Results · Table 1; Fig. S4

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BET surface areaMarked as a best value within this paper	12.9	—	—	Table Exact Reported	6 · Table 1 · Table 1
BJH pore volume	0.132	—	—	Text Exact Reported	7 · 3. Results and discussion · Fig. S4
tap density	1.74	—	—	Table Exact Reported	6 · Table 1 · Table 1
mesopore diameter range	5 to 10 nm	—	—	Text Range	7 · 3. Results and discussion · Fig. S4
BJH pore size from SI inset	4.47	—	—	Figure Axis Rounded Reported	3 · Appendix A. Supporting Information · Fig. S4e

N2 adsorption/desorption isotherm; BET surface area; pore-size distribution

Gas sorption and porosity

DTA-Ni-Mn-MOFs · Powder

Supporting Information adsorption-desorption isotherm for prepared Ni-Mn-MOF precursor

Temperature: 77
Atmosphere: N2
Context: pristine mixed-metal MOF precursor
Measurement source: 5 · Appendix A. Supporting Information · Fig. S7

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BET surface area	842.1	—	—	Figure Axis Rounded Reported	5 · Appendix A. Supporting Information · Fig. S7c
pore size	19.8	—	—	Figure Axis Rounded Reported	5 · Appendix A. Supporting Information · Fig. S7c
pore volumeMarked as a best value within this paper	1.766	—	—	Figure Axis Rounded Reported	5 · Appendix A. Supporting Information · Fig. S7c

N2 adsorption/desorption; BET; BJH pore volume; tap density

Gas sorption and porosity

DTA-LNMO powder · Powder

BET measured with ASAP 2020 at liquid nitrogen temperature (77 K); isotherms classified as type IV with narrow mesopores 5-10 nm.

Temperature: 77
Atmosphere: N2
Geometry: powder sorption
Context: derived LNMO powder
Measurement source: 6-7 · 2.2 Materials characterization / 3. Results · Table 1; Fig. S4

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BET surface area	9.0	—	—	Table Exact Reported	6 · Table 1 · Table 1
BJH pore volume	0.137	—	—	Text Exact Reported	7 · 3. Results and discussion · Fig. S4
tap density	2.01	—	—	Table Exact Reported	6 · Table 1 · Table 1
mesopore diameter range	5 to 10 nm	—	—	Text Range	7 · 3. Results and discussion · Fig. S4
BJH pore size from SI inset	6.32	—	—	Figure Axis Rounded Reported	3 · Appendix A. Supporting Information · Fig. S4c

N2 adsorption/desorption isotherm; BET surface area; pore-size distribution

Gas sorption and porosity

OBA-Ni-Mn-MOFs · Powder

Supporting Information adsorption-desorption isotherm for prepared Ni-Mn-MOF precursor

Temperature: 77
Atmosphere: N2
Context: pristine mixed-metal MOF precursor
Measurement source: 5 · Appendix A. Supporting Information · Fig. S7

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BET surface area	361.1	—	—	Figure Axis Rounded Reported	5 · Appendix A. Supporting Information · Fig. S7d
pore size	10.07	—	—	Figure Axis Rounded Reported	5 · Appendix A. Supporting Information · Fig. S7d
pore volume	0.547	—	—	Figure Axis Rounded Reported	5 · Appendix A. Supporting Information · Fig. S7d

N2 adsorption/desorption; BET; BJH pore volume; tap density

Gas sorption and porosity

OBA-LNMO powder · Powder

BET measured with ASAP 2020 at liquid nitrogen temperature (77 K); isotherms classified as type IV with narrow mesopores 5-10 nm.

Temperature: 77
Atmosphere: N2
Geometry: powder sorption
Context: derived LNMO powder
Measurement source: 6-7 · 2.2 Materials characterization / 3. Results · Table 1; Fig. S4

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BET surface area	7.1	—	—	Table Exact Reported	6 · Table 1 · Table 1
BJH pore volume	0.148	—	—	Text Exact Reported	7 · 3. Results and discussion · Fig. S4
tap density	1.89	—	—	Table Exact Reported	6 · Table 1 · Table 1
mesopore diameter range	5 to 10 nm	—	—	Text Range	7 · 3. Results and discussion · Fig. S4
BJH pore size from SI inset	8.64	—	—	Figure Axis Rounded Reported	3 · Appendix A. Supporting Information · Fig. S4d

N2 adsorption/desorption isotherm; BET surface area; pore-size distribution

Gas sorption and porosity

PTA-Ni-Mn-MOFs · Powder

Supporting Information adsorption-desorption isotherm for prepared Ni-Mn-MOF precursor

Temperature: 77
Atmosphere: N2
Context: pristine mixed-metal MOF precursor
Measurement source: 5 · Appendix A. Supporting Information · Fig. S7

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BET surface area	369.7	—	—	Figure Axis Rounded Reported	5 · Appendix A. Supporting Information · Fig. S7a
pore size	12.05	—	—	Figure Axis Rounded Reported	5 · Appendix A. Supporting Information · Fig. S7a
pore volume	0.686	—	—	Figure Axis Rounded Reported	5 · Appendix A. Supporting Information · Fig. S7a

N2 adsorption/desorption; BET; BJH pore volume; tap density

Gas sorption and porosity

PTA-LNMO powder · Powder

BET measured with ASAP 2020 at liquid nitrogen temperature (77 K); isotherms classified as type IV with narrow mesopores 5-10 nm.

Temperature: 77
Atmosphere: N2
Geometry: powder sorption
Context: derived LNMO powder
Measurement source: 6-7 · 2.2 Materials characterization / 3. Results · Table 1; Fig. S4

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BET surface area	8.1	—	—	Table Exact Reported	6 · Table 1 · Table 1
BJH pore volume	0.108	—	—	Text Exact Reported	7 · 3. Results and discussion · Fig. S4
tap density	2.27	—	—	Table Exact Reported	6 · Table 1 · Table 1
mesopore diameter range	5 to 10 nm	—	—	Text Range	7 · 3. Results and discussion · Fig. S4
BJH pore size from SI inset	5.42	—	—	Figure Axis Rounded Reported	3 · Appendix A. Supporting Information · Fig. S4a

N2 adsorption/desorption isotherm; BET surface area; pore-size distribution

Gas sorption and porosity

PTCDA-Ni-Mn-MOFs · Powder

Supporting Information adsorption-desorption isotherm for prepared Ni-Mn-MOF precursor

Temperature: 77
Atmosphere: N2
Context: pristine mixed-metal MOF precursor
Measurement source: 5 · Appendix A. Supporting Information · Fig. S7

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BET surface area	609.3	—	—	Figure Axis Rounded Reported	5 · Appendix A. Supporting Information · Fig. S7f
pore size	8.23	—	—	Figure Axis Rounded Reported	5 · Appendix A. Supporting Information · Fig. S7f
pore volume	0.751	—	—	Figure Axis Rounded Reported	5 · Appendix A. Supporting Information · Fig. S7f

N2 adsorption/desorption; BET; BJH pore volume; tap density

Gas sorption and porosity

PTCDA-LNMO powder · Powder

BET measured with ASAP 2020 at liquid nitrogen temperature (77 K); isotherms classified as type IV with narrow mesopores 5-10 nm.

Temperature: 77
Atmosphere: N2
Geometry: powder sorption
Context: derived LNMO powder
Measurement source: 6-7 · 2.2 Materials characterization / 3. Results · Table 1; Fig. S4

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BET surface area	9.9	—	—	Table Exact Reported	6 · Table 1 · Table 1
BJH pore volumeMarked as a best value within this paper	0.235	—	—	Text Exact Reported	7 · 3. Results and discussion · Fig. S4
tap densityMarked as a best value within this paper	2.47	—	—	Table Exact Reported	6 · Table 1 · Table 1
mesopore diameter range	5 to 10 nm	—	—	Text Range	7 · 3. Results and discussion · Fig. S4
BJH pore size from SI insetMarked as a best value within this paper	9.57	—	—	Figure Axis Rounded Reported	3 · Appendix A. Supporting Information · Fig. S4f

N2 adsorption/desorption isotherm; BET surface area; pore-size distribution

Gas sorption and porosity

TCA-Ni-Mn-MOFs · Powder

Supporting Information adsorption-desorption isotherm for prepared Ni-Mn-MOF precursor

Temperature: 77
Atmosphere: N2
Context: pristine mixed-metal MOF precursor
Measurement source: 5 · Appendix A. Supporting Information · Fig. S7

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BET surface area	595.6	—	—	Figure Axis Rounded Reported	5 · Appendix A. Supporting Information · Fig. S7b
pore size	10.6	—	—	Figure Axis Rounded Reported	5 · Appendix A. Supporting Information · Fig. S7b
pore volume	0.953	—	—	Figure Axis Rounded Reported	5 · Appendix A. Supporting Information · Fig. S7b

N2 adsorption/desorption; BET; BJH pore volume; tap density

Gas sorption and porosity

TCA-LNMO powder · Powder

BET measured with ASAP 2020 at liquid nitrogen temperature (77 K); isotherms classified as type IV with narrow mesopores 5-10 nm.

Temperature: 77
Atmosphere: N2
Geometry: powder sorption
Context: derived LNMO powder
Measurement source: 6-7 · 2.2 Materials characterization / 3. Results · Table 1; Fig. S4

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BET surface area	7.0	—	—	Table Exact Reported	6 · Table 1 · Table 1
BJH pore volume	0.124	—	—	Text Exact Reported	7 · 3. Results and discussion · Fig. S4
tap density	2.18	—	—	Table Exact Reported	6 · Table 1 · Table 1
mesopore diameter range	5 to 10 nm	—	—	Text Range	7 · 3. Results and discussion · Fig. S4
BJH pore size from SI inset	6.05	—	—	Figure Axis Rounded Reported	3 · Appendix A. Supporting Information · Fig. S4b