Electrical Transport — Linker-Based Bandgap Tuning in Conductive MOF Solid Solutions

3 measurement groups · 15 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Cu3(TATHB)2 / Cu-TATHB (x = 0) · Pellet

Pressed 5 mm pellets under 1.5 tons; thickness measured by caliper; ambient conditions for bulk conductivity trend.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Bulk electrical conductivity Cu3(TATHB)2	4.2 x 10^-8 S cm^-1	—	—	Text Exact Reported	p004 · Tuning of Electronic Properties · Figure 5c
Bulk electrical conductivity Cu3(HAB)0.5(TATHB)1.5	~0.25 uS cm^-1 (~2.5 x 10^-7 S cm^-1)	—	—	Figure Axis Approximate	p009 · Tuning of Electronic Properties · Figure 5c
Bulk electrical conductivity Cu3(HAB)(TATHB)	~1.7 uS cm^-1 (~1.7 x 10^-6 S cm^-1)	—	—	Figure Axis Approximate	p009 · Tuning of Electronic Properties · Figure 5c
Bulk electrical conductivity Cu3(HAB)1.5(TATHB)0.5	~16 uS cm^-1 (~1.6 x 10^-5 S cm^-1)	—	—	Figure Axis Approximate	p009 · Tuning of Electronic Properties · Figure 5c
Bulk electrical conductivity Cu3(HAB)2Marked as a best value within this paper	2.9 x 10^-5 S cm^-1	—	—	Text Exact Reported	p004 · Tuning of Electronic Properties · Figure 5c

Physically blended Cu-TATHB/Cu-HAB mixtures · Pellet

Mechanically blended Cu-TATHB/Cu-HAB mixtures measured as a control; conditions otherwise analogous to pellet conductivity.

Temperature: 293
Atmosphere: ambient
Geometry: pressed pellet, physical mixture
Context: physical mixture control, not single-phase solid solution
Measurement source: S15 · Electrical conductivity of physical mixed Cu-HAB and Cu-TATHB · Figure S12

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Physical mixture conductivity HAB ratio 0	~0.04 uS cm^-1	—	—	Figure Axis Approximate	S15 · Electrical conductivity of physical mixed Cu-HAB and Cu-TATHB · Figure S12
Physical mixture conductivity HAB ratio 05	~10 uS cm^-1	—	—	Figure Axis Approximate	S15 · Electrical conductivity of physical mixed Cu-HAB and Cu-TATHB · Figure S12
Physical mixture conductivity HAB ratio 1	~45 uS cm^-1	—	—	Figure Axis Approximate	S15 · Electrical conductivity of physical mixed Cu-HAB and Cu-TATHB · Figure S12
Physical mixture conductivity HAB ratio 15	~50 uS cm^-1	—	—	Figure Axis Approximate	S15 · Electrical conductivity of physical mixed Cu-HAB and Cu-TATHB · Figure S12
Physical mixture conductivity HAB ratio 2	~28 uS cm^-1	—	—	Figure Axis Approximate	S15 · Electrical conductivity of physical mixed Cu-HAB and Cu-TATHB · Figure S12

Cu3(TATHB)2 / Cu-TATHB (x = 0) · Pellet

Temperature range 293-343 K under vacuum; sigma = sigma0 exp(-Ea/kBT).

Temperature: 293-343
Atmosphere: vacuum
Geometry: pressed pellet
Context: pristine solid-solution powders
Measurement source: p003-p004 · Electronic Properties Characterizations; Tuning of Electronic Properties · Figure 2b; Figure 5d

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Arrhenius activation energy Cu3(TATHB)2	0.33 eV	—	—	Text Exact Reported	p003 · Electronic Properties Characterizations · Figure 2b
Arrhenius activation energy Cu3(HAB)0.5(TATHB)1.5	~0.275 eV	—	—	Figure Axis Approximate	p009 · Tuning of Electronic Properties · Figure 5d
Arrhenius activation energy Cu3(HAB)(TATHB)	~0.245 eV	—	—	Figure Axis Approximate	p009 · Tuning of Electronic Properties · Figure 5d
Arrhenius activation energy Cu3(HAB)1.5(TATHB)0.5	~0.21 eV	—	—	Figure Axis Approximate	p009 · Tuning of Electronic Properties · Figure 5d
Arrhenius activation energy Cu3(HAB)2	~0.18 eV	—	—	Figure Axis Approximate	p009 · Tuning of Electronic Properties · Figure 5d