cMOF Evidence Base
Electrochemistry Application — Linker-Based Bandgap Tuning in Conductive MOF Solid Solutions

Measurement evidence

Electrochemistry Application

Linker-Based Bandgap Tuning in Conductive MOF Solid Solutions · Choi J.Y., Wang M., Check B. et al. · Small · 2023 · 2206988

1 measurement group · 11 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Cyclic voltammetry for LUMO/onset reduction potential

Voltammetry

Cu3(TATHB)2 / Cu-TATHB (x = 0) · Pellet

MOF ink drop-cast on glassy carbon; Ag/Ag+ reference; Pt wire counter; 0.1 M TBAPF6 acetonitrile electrolyte; scan rate 100 mV s^-1.

Geometry
glassy carbon working electrode with drop-cast MOF/PTFE/Super P ink
Context
electrode films made from pristine MOF powders plus conductive carbon/binder for electrochemistry
Measurement source
S2-S3 · Measurement of LUMO using cyclic voltammetry · Figure 5a; Figure S11
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Onset reduction potential range with HAB ratioshifted from -1.09 V to -1.16 V as HAB ratio increases——Text
Range		p003 · Tuning of Electronic Properties · Figure 5a; Figure S11
HOMO energy Cu3(TATHB)2~-4.53 eV——Figure Axis
Approximate		p009 · Tuning of Electronic Properties · Figure 5b
HOMO energy Cu3(HAB)0.5(TATHB)1.5~-4.51 eV——Figure Axis
Approximate		p009 · Tuning of Electronic Properties · Figure 5b
HOMO energy Cu3(HAB)(TATHB)~-4.48 eV——Figure Axis
Approximate		p009 · Tuning of Electronic Properties · Figure 5b
HOMO energy Cu3(HAB)1.5(TATHB)0.5~-4.45 eV——Figure Axis
Approximate		p009 · Tuning of Electronic Properties · Figure 5b
HOMO energy Cu3(HAB)2~-4.38 eV——Figure Axis
Approximate		p009 · Tuning of Electronic Properties · Figure 5b
LUMO energy Cu3(TATHB)2~-3.55 eV——Figure Axis
Approximate		p009 · Tuning of Electronic Properties · Figure 5b
LUMO energy Cu3(HAB)0.5(TATHB)1.5~-3.55 eV——Figure Axis
Approximate		p009 · Tuning of Electronic Properties · Figure 5b
LUMO energy Cu3(HAB)(TATHB)~-3.54 eV——Figure Axis
Approximate		p009 · Tuning of Electronic Properties · Figure 5b
LUMO energy Cu3(HAB)1.5(TATHB)0.5~-3.53 eV——Figure Axis
Approximate		p009 · Tuning of Electronic Properties · Figure 5b
LUMO energy Cu3(HAB)2~-3.47 eV——Figure Axis
Approximate		p009 · Tuning of Electronic Properties · Figure 5b