Electrical Transport — Regulating Crystallization and Lead Leakage of Perovskite Solar Cell Via Novel Polyoxometalate-Based Metal–Organic Framework

4 measurement groups · 17 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

POMOF heated at 300 degC · Powder

POMOF morphology and surface-potential distribution after 10 min visible-light illumination.

Context: pristine POMOF
Measurement source: p002-p003 · 2.1 Structure and Properties of POMOF · Figure 1b-d

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
KPFM potential change after illumination	45 mV after visible-light illumination for 10 min	—	—	Text Rounded Reported	p002 · 2.1 Structure and Properties of POMOF · Figure 1c,d
AFM particle size	about 290 nm	—	—	Text Approximate	p002 · 2.1 Structure and Properties of POMOF · Figure 1b

POMOF-functionalised perovskite film · Thin Film

Trap-filled-limited voltage and trap density; electron-only FTO/TiO2/perovskite/PCBM/Ag.

Atmosphere: dark
Geometry: FTO/TiO2/perovskite/PCBM/Ag
Context: composite film vs pristine control
Measurement source: p006 · 2.4 Effect of POMOF on Charge Transport Dynamics · Figure 4a

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
trap density electron-only, control film	1.56 x 10^16 cm-3	—	—	Text Exact Reported	p006 · 2.4 Effect of POMOF on Charge Transport Dynamics · Figure 4a
trap density electron-only, POMOF film	1.14 x 10^16 cm-3	—	—	Text Exact Reported	p006 · 2.4 Effect of POMOF on Charge Transport Dynamics · Figure 4a
VTFL electron-only, control film	0.83 V	—	—	Text Exact Reported	p006 · 2.4 Effect of POMOF on Charge Transport Dynamics · Figure 4a
VTFL electron-only, POMOF film	0.61 V	—	—	Text Exact Reported	p006 · 2.4 Effect of POMOF on Charge Transport Dynamics · Figure 4a

POMOF-functionalised perovskite film · Thin Film

Trap-filled-limited voltage and trap density; hole-only FTO/PEDOT:PSS/perovskite/Spiro-OMeTAD/Au.

Atmosphere: dark
Geometry: FTO/PEDOT:PSS/perovskite/Spiro-OMeTAD/Au
Context: composite film vs pristine control
Measurement source: p006 · 2.4 Effect of POMOF on Charge Transport Dynamics · Figure 4b

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
trap density hole-only, control film	1.52 x 10^16 cm-3	—	—	Text Exact Reported	p006 · 2.4 Effect of POMOF on Charge Transport Dynamics · Figure 4b
trap density hole-only, POMOF film	1.19 x 10^16 cm-3	—	—	Text Exact Reported	p006 · 2.4 Effect of POMOF on Charge Transport Dynamics · Figure 4b
VTFL hole-only, control film	0.81 V	—	—	Text Exact Reported	p006 · 2.4 Effect of POMOF on Charge Transport Dynamics · Figure 4b
VTFL hole-only, POMOF film	0.64 V	—	—	Text Exact Reported	p006 · 2.4 Effect of POMOF on Charge Transport Dynamics · Figure 4b

POMOF-functionalised perovskite film · Thin Film

Top-view SEM/AFM and KPFM/C-AFM compare control and POMOF-functionalised perovskite films.

Context: composite film vs pristine control
Measurement source: p005 · 2.3 Regulation of Perovskite Crystallization With POMOF · Figure 3; Figures S13-S15

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
C-AFM conductivity comparison	POMOF-functionalised perovskite film exhibits much higher conductivity than control	—	—	Text Qualitative	p005 · 2.3 Regulation of Perovskite Crystallization With POMOF · Figure S15
average grain size, control	261 nm	—	—	Text Exact Reported	p005 · 2.3 Regulation of Perovskite Crystallization With POMOF · Figure 3g; Figure S13
average grain size, POMOF film	375 nm	—	—	Text Exact Reported	p005 · 2.3 Regulation of Perovskite Crystallization With POMOF · Figure 3i; Figure S13
surface contact potential, control	-701 mV	—	—	Text Exact Reported	p005 · 2.3 Regulation of Perovskite Crystallization With POMOF · Figure 3h,j
surface contact potential, POMOF film	-782 mV	—	—	Text Exact Reported	p005 · 2.3 Regulation of Perovskite Crystallization With POMOF · Figure 3h,j
RMS roughness, control	15.7 nm	—	—	Text Exact Reported	p005 · 2.3 Regulation of Perovskite Crystallization With POMOF · Figure S14
RMS roughness, POMOF film	20.5 nm	—	—	Text Exact Reported	p005 · 2.3 Regulation of Perovskite Crystallization With POMOF · Figure S14