cMOF Evidence Base
Electrochemistry Application — Microscopic Insights into Cation-Coupled Electron Hopping Transport in a Metal-Organic Framework

Measurement evidence

Electrochemistry Application

Microscopic Insights into Cation-Coupled Electron Hopping Transport in a Metal-Organic Framework · Castner A.T., Su H., Svensson Grape E. et al. · Journal of the American Chemical Society · 2022 · 5910-5920

2 measurement groups · 18 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

cyclic voltammetry (homogeneous linker)

Voltammetry

dcphOH-NDI homogeneous linker solution · Unknown

dcphOH-NDI in 0.5 M LiClO4, KPF6 or TBAPF6 in DMF/EtOH/THF; 50 mV s-1; potentials vs Fc+/0.

Atmosphere
Ar-sparged nonaqueous electrolyte
Geometry
glassy carbon working electrode, 0.071 cm2
Context
homogeneous linker model control
Measurement source
5914 · Results/Discussion · Figure 3; Table 1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
dcphOH-NDI E1/2 NDI0/radical-anion, KPF6 in DMF-0.95 V vs Fc+/0——Table
Exact Reported		5914 · Results/Discussion · Table 1
dcphOH-NDI E1/2 NDI0/radical-anion, LiClO4 in DMF-0.93 V vs Fc+/0——Table
Exact Reported		5914 · Results/Discussion · Table 1
dcphOH-NDI E1/2 NDI0/radical-anion, LiClO4 in EtOH-0.81 V vs Fc+/0——Table
Exact Reported		5914 · Results/Discussion · Table 1
dcphOH-NDI E1/2 NDI0/radical-anion, LiClO4 in THF-0.86 V vs Fc+/0——Table
Exact Reported		5914 · Results/Discussion · Table 1
dcphOH-NDI E1/2 NDI0/radical-anion, TBAPF6 in DMF-0.94 V vs Fc+/0——Table
Exact Reported		5914 · Results/Discussion · Table 1
dcphOH-NDI E1/2 NDI0/radical-anion, TBAPF6 in THF-0.97 V vs Fc+/0——Table
Exact Reported		5914 · Results/Discussion · Table 1
dcphOH-NDI E1/2 radical-anion/dianion, KPF6 in DMF-1.33 V vs Fc+/0——Table
Exact Reported		5914 · Results/Discussion · Table 1
dcphOH-NDI E1/2 radical-anion/dianion, LiClO4 in DMF-1.25 V vs Fc+/0——Table
Exact Reported		5914 · Results/Discussion · Table 1
dcphOH-NDI E1/2 radical-anion/dianion, LiClO4 in EtOH-1.00 V vs Fc+/0——Table
Exact Reported		5914 · Results/Discussion · Table 1
dcphOH-NDI E1/2 radical-anion/dianion, LiClO4 in THF-0.95 V vs Fc+/0——Table
Exact Reported		5914 · Results/Discussion · Table 1
dcphOH-NDI E1/2 radical-anion/dianion, TBAPF6 in DMF-1.33 V vs Fc+/0——Table
Exact Reported		5914 · Results/Discussion · Table 1
dcphOH-NDI E1/2 radical-anion/dianion, TBAPF6 in THF-1.27 V vs Fc+/0——Table
Exact Reported		5914 · Results/Discussion · Table 1

cyclic voltammetry (MOF thin film)

Voltammetry

Zr(dcphOH-NDI)@FTO thin-film electrodes · Electrode

Zr(dcphOH-NDI)@FTO in 0.5 M LiClO4, KPF6 or TBAPF6 in DMF; 50 mV s-1; potentials vs Fc+/0.

Atmosphere
Ar-degassed nonaqueous electrolyte; N2-dried film before insertion
Geometry
MOF-modified FTO working electrode with about 1 cm2 exposed film
Context
pristine framework on FTO
Measurement source
5915 · Results/Discussion · Figure 4; Table 2
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Zr(dcphOH-NDI)@FTO E1/2 NDI0/radical-anion, KPF6 in DMF-0.97 V vs Fc+/0——Table
Exact Reported		5915 · Results/Discussion · Table 2
Zr(dcphOH-NDI)@FTO E1/2 NDI0/radical-anion, LiClO4 in DMF-0.95 V vs Fc+/0——Table
Exact Reported		5915 · Results/Discussion · Table 2
Zr(dcphOH-NDI)@FTO E1/2 NDI0/radical-anion, TBAPF6 in DMF-1.04 V vs Fc+/0——Table
Exact Reported		5915 · Results/Discussion · Table 2
Zr(dcphOH-NDI)@FTO E1/2 radical-anion/dianion, KPF6 in DMF-1.30 V vs Fc+/0——Table
Exact Reported		5915 · Results/Discussion · Table 2
Zr(dcphOH-NDI)@FTO E1/2 radical-anion/dianion, LiClO4 in DMF-1.21 V vs Fc+/0——Table
Exact Reported		5915 · Results/Discussion · Table 2
Zr(dcphOH-NDI)@FTO E1/2 radical-anion/dianion, TBAPF6 in DMF-1.34 V vs Fc+/0——Table
Exact Reported		5915 · Results/Discussion · Table 2