Porosity — Design and synthesis of hydroxide ion-conductive metal-organic frameworks based on salt inclusion

6 measurement groups · 12 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

NBu4-ZIF-8-OH powder · Powder

CO2 adsorption at 298 K compared NBu4-ZIF-8 and NBu4-ZIF-8-OH.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Approximate CO2 adsorption of NBu4-ZIF-8 near 95 kPa	about 0.63 mmol g-1 at ca. 95 kPa	—	visual estimate from Figure 3 axis	Figure Axis Approximate	1704 · Figure 3 · Figure 3
Approximate CO2 adsorption of NBu4-ZIF-8-OH near 95 kPa	about 0.82 mmol g-1 at ca. 95 kPa	—	visual estimate from Figure 3 axis	Figure Axis Approximate	1704 · Figure 3 · Figure 3
OH- concentration in NBu4-ZIF-8-OH	0.21 mmol g-1	—	—	Text Exact Reported	1704 · Ion exchange · Figure 3
Replacement of initially included HCO3- ions by OH-	47%	—	—	Text Exact Reported	1704 · Ion exchange · Figure 3

NBu4-ZIF-8 powder · Powder

77 K; samples dried at room temperature under vacuum overnight.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BET surface area of NBu4-ZIF-8	871 m2 g-1	—	—	Text Exact Reported	1703 · Porosity · Figure S7
BET surface area reduction by salt inclusion	reduced by 52%	—	—	Text Exact Reported	1703 · Porosity · Figure S7
BET surface area reduction by salt inclusion on molar basis	61%, calculated on the basis of units of m2 mol-1	—	—	Text Exact Reported	1703 · Porosity · Figure S7
Unoccupied cage fraction after salt inclusion	30% of cages were not occupied by the salt	—	—	Text Rounded Reported	1703 · Porosity · Figure S7

NBu4-ZIF-8-OH powder · Powder

77 K; NBu4-ZIF-8-OH transferred to measurement tube inside glovebox to avoid air exposure.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BET surface area of NBu4-ZIF-8-OH	868 m2 g-1	—	—	Text Exact Reported	1704 · Porosity and ion exchange · Figure S7

ZIF-8 powder · Powder

77 K; samples dried at room temperature under vacuum overnight.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BET surface area of ZIF-8	1664 m2 g-1	—	—	Text Exact Reported	1703 · Porosity · Figure S7

NBu4-ZIF-8-OH powder · Powder

298 K water vapour adsorption/desorption.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Approximate water vapour adsorption of NBu4-ZIF-8-OH near P/P0 0.95	about 75 cm3 g-1 near P/P0 0.95	—	visual estimate from Figure S9 axis	Figure Axis Approximate	S11 · Figure S9 · Figure S9

ZIF-8 powder · Powder

298 K water vapour adsorption/desorption.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Approximate water vapour adsorption of ZIF-8 near P/P0 0.95	about 36 cm3 g-1 near P/P0 0.95	—	visual estimate from Figure S9 axis	Figure Axis Approximate	S11 · Figure S9 · Figure S9