Measurement evidence
Redox-Active 1D Coordination Polymers of Iron-Sulfur Clusters · Horwitz N.E., Xie J., Filatov A.S. et al. · Journal of the American Chemical Society · 2019 · 3940-3951
Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.
Compound 1 as-synthesized black powder · Powder
As-synthesized compound 1; pressed pellet/solid clamped between brass electrodes; room temperature; under N2; triplicate separate batches where stated.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Electrical conductivity of as-synthesized 1 | 3(3) x 10^-11 S/cm | — | 3 x 10^-11 S/cm | Text Exact Reported | 3944 · Electronic Properties |
Compound 1 oxidatively treated solid · Powder
Oxidatively treated compound 1; pressed pellet/solid clamped between brass electrodes; room temperature; under N2; triplicate separate batches where stated.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Electrical conductivity of oxidatively treated 1 | 7(5) x 10^-12 S/cm | — | 5 x 10^-12 S/cm | Text Exact Reported | 3944 · Electronic Properties |
Compound 1 reductively doped solid · Powder
Reductively doped compound 1; pressed pellet/solid clamped between brass electrodes; room temperature; under N2; triplicate separate batches where stated.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Electrical conductivity of reductively doped 1 | 6(2) x 10^-9 S/cm | — | 2 x 10^-9 S/cm | Text Exact Reported | 3944 · Electronic Properties |
Compound 2 as-synthesized black powder · Powder
As-synthesized compound 2; pressed pellet/solid clamped between brass electrodes; room temperature; under N2; triplicate separate batches where stated.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Electrical conductivity of as-synthesized 2 | 5(3) x 10^-10 S/cm | — | 3 x 10^-10 S/cm | Text Exact Reported | 3944 · Electronic Properties |
Compound 2 oxidatively treated solid · Powder
Oxidatively treated compound 2; pressed pellet/solid clamped between brass electrodes; room temperature; under N2; triplicate separate batches where stated.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Electrical conductivity of oxidatively treated 2 | 7(1) x 10^-10 S/cm | — | 1 x 10^-10 S/cm | Text Exact Reported | 3944 · Electronic Properties |
Compound 2 reductively doped solid · Powder
Reductively doped compound 2; pressed pellet/solid clamped between brass electrodes; room temperature; under N2; triplicate separate batches where stated.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Electrical conductivity of reductively doped 2Marked as a best value within this paper | 5(2) x 10^-6 S/cm | — | 2 x 10^-6 S/cm | Text Exact Reported | 3944 · Electronic Properties |
2 precipitated from DMF solution without reductant · Powder
DMF-solution precipitated compound 2 without reductant; pressed pellet/solid clamped between brass electrodes; room temperature; under N2; triplicate separate batches where stated.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Electrical conductivity of 2 precipitated from DMF without reductant | 3(4) x 10^-9 S/cm | — | 4 x 10^-9 S/cm | Text Exact Reported | 3945 · Electronic Properties |
Partially reduced 2 precipitated from DMF solution · Powder
Solution-reduced, Et2O-precipitated compound 2; pressed pellet/solid clamped between brass electrodes; room temperature; under N2; triplicate separate batches where stated.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Electrical conductivity of solution-reduced, reprecipitated 2Marked as a best value within this paper | 1.5(5) x 10^-5 S/cm | — | 0.5 x 10^-5 S/cm | Text Exact Reported | 3945 · Electronic Properties |
[Fe4S4(SPh)4][TBA]2 precursor control · Powder
[Fe4S4(SPh)4][TBA]2 molecular precursor control; pressed pellet/solid clamped between brass electrodes; room temperature; under N2; triplicate separate batches where stated.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Electrical conductivity upper bound of [Fe4S4(SPh)4][TBA]2 precursor | both below 10^-12 S/cm | — | — | Text Approximate | 3944 · Electronic Properties |
[Fe4S4(SPh)4][TMA]2 precursor control · Powder
[Fe4S4(SPh)4][TMA]2 molecular precursor control; pressed pellet/solid clamped between brass electrodes; room temperature; under N2; triplicate separate batches where stated.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Electrical conductivity upper bound of [Fe4S4(SPh)4][TMA]2 precursor | both below 10^-12 S/cm | — | — | Text Approximate | 3944 · Electronic Properties |