Electrochemistry Application — Redox-Active 1D Coordination Polymers of Iron-Sulfur Clusters

2 measurement groups · 5 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Compound 2 in DMF solution · Unknown

DMF, 0.1 M [Li][CF3SO3], 0.1 V/s; potentials versus FeCp2+/FeCp2.

Temperature: room temperature
Atmosphere: inert
Geometry: Glassy carbon working electrode, platinum wire counter electrode, silver wire pseudoreference
Context: Redox activity of pristine 2 in solution.
Measurement source: 3944 · Electronic Properties · Figure 6

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
First reductive feature of 2 in LiCF3SO3 electrolyte	-1.6 V vs FeCp2+/FeCp2	—	—	Text Rounded Reported	3944 · Electronic Properties · Figure 6
Second reductive feature of 2 in LiCF3SO3 electrolyte	-2.2 V vs FeCp2+/FeCp2	—	—	Text Rounded Reported	3944 · Electronic Properties · Figure 6
Irreversible oxidation feature of Fe4S4-BDT chains	approximately -0.3 V vs FeCp2+/FeCp2	—	—	Text Approximate	3944 · Electronic Properties · Figure 6; Figures S43-S46

Compound 2 in DMF solution · Unknown

DMF, 0.1 M [TMA][PF6]; 2 forms a fine suspension; potentials versus FeCp2+/FeCp2.

Temperature: room temperature
Atmosphere: inert
Geometry: Glassy carbon working electrode, platinum wire counter electrode, silver wire pseudoreference
Context: Redox activity of 2 suspension compared with monomer.
Measurement source: 3944 · Electronic Properties · Figure S44

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
First quasi-reversible reduction in TMAPF6 electrolyte	-1.43 V vs FeCp2+/FeCp2	—	—	Text Rounded Reported	3944 · Electronic Properties · Figure S44
Second quasi-reversible reduction in TMAPF6 electrolyte	-2.13 V vs FeCp2+/FeCp2	—	—	Text Rounded Reported	3944 · Electronic Properties · Figure S44