Other — Redox-Active 1D Coordination Polymers of Iron-Sulfur Clusters

6 measurement groups · 12 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Compound 1 as-synthesized black powder · Powder

Residual Li in as-synthesized compound 1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Residual Li content in as-synthesized 1	1.4(7)%	—	0.7%	SI Table Exact Reported	S5 · ICP-MS Analysis · Table S1

Compound 1 after [TBA][PF6] treatment · Powder

Residual Li after [TBA][PF6] treatment of compound 1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Li content in 1 after [R4N][PF6] treatment	0.59%	—	—	SI Table Exact Reported	S5 · ICP-MS Analysis · Table S1

Compound 2 as-synthesized black powder · Powder

Residual Li in as-synthesized compound 2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Residual Li content in as-synthesized 2	7(3)%	—	3%	SI Table Exact Reported	S5 · ICP-MS Analysis · Table S1

Compound 2 after [TMA][PF6] treatment · Powder

Residual Li after [TMA][PF6] treatment of compound 2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Li content in 2 after [R4N][PF6] treatment	2.84%	—	—	SI Table Exact Reported	S5 · ICP-MS Analysis · Table S1

Compound 1 reductively doped solid · Powder

Reduced solid-state compound 1; Li/Co uptake and reduction degree

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Co/Fe4S4 after reduction for 1	1.2(3)%	—	0.3%	Table Exact Reported	3944 · Electronic Properties · Table 1
Li/Fe4S4 after reduction for 1	9(1)%	—	1%	Table Exact Reported	3944 · Electronic Properties · Table 1
Li/Fe4S4 before reduction for 1	3(1)%	—	1%	Table Exact Reported	3944 · Electronic Properties · Table 1
Degree of reduction in solid-state reduced 1	7(2)%	0.07 electrons per formula unit	2%	Table Exact Reported	3944 · Electronic Properties · Table 1

Compound 2 reductively doped solid · Powder

Reduced solid-state compound 2; Li/Co uptake and reduction degree

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Co/Fe4S4 after reduction for 2	9.0(6)%	—	0.6%	Table Exact Reported	3944 · Electronic Properties · Table 1
Li/Fe4S4 after reduction for 2	28(4)%	—	4%	Table Exact Reported	3944 · Electronic Properties · Table 1
Li/Fe4S4 before reduction for 2	14(5)%	—	5%	Table Exact Reported	3944 · Electronic Properties · Table 1
Degree of reduction in solid-state reduced 2	24(6)%	0.24 electrons per formula unit	6%	Table Exact Reported	3944 · Electronic Properties · Table 1