Guo L., Sun J., Sun X. et al. · Nanoscale Advances · 2019 · 4688-4691
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
Ni-CAT nanorod electrodes combine high reversible capacity, rate capability and 200-cycle stability as LIB anodes.
Caveat: Performance is for composite electrodes containing carbon black and CMC, not a neat pressed Ni-CAT framework.
4 · Summary · Fig. 4 · Linked to 4 structured results
The hydrothermal product is 1D Ni-CAT nanorods with a layered hexagonal honeycomb Ni-HHTP framework and evenly distributed Ni, O and C.
Caveat: No CIF or Rietveld refinement was supplied; assignment is based on XRD, spectroscopy and microscopy.
2 · Results · Fig. 1; Fig. 2 · Linked to 6 structured results
The authors attribute fast lithium diffusion to the 1D porous MOF structure, which provides efficient channels for Li+ ions.
Caveat: Mechanistic attribution is interpretive; no direct pore-resolved diffusion measurement is shown.
2 · Results · Fig. 3; Fig. S1 · Linked to 4 structured results
Ni-CAT nanorod electrodes show fast Li+ diffusion, with discharge DLi on the order of 10^-9 cm2 s-1 and charge DLi on the order of 10^-10 cm2 s-1.
Caveat: The reported values are order-of-magnitude GITT-derived estimates, not direct electronic conductivity measurements.
2 · Results · Fig. 3 · Linked to 3 structured results
Lithium storage mainly involves reversible insertion/de-insertion in organic ligands and pores, with possible contributions from benzene rings, pores and interlaminar space; Ni2+ is preserved and is not the active redox centre.
Caveat: The mechanism is proposed from ex situ/indirect evidence and is described as tentative by the authors.
3 · Results · Fig. 4b; Fig. S4-S6 · Linked to 5 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| 1D conductive Ni-CAT nanorodsBrowse family: Ni₃(HHTP)₂ / Ni–HHTP | Ni-CAT; Ni(II)-HHTP conductive MOF, exact empirical formula not reportedNi(II) ions coordinated by catecholate oxygens · 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP) | 2D · PristineLayered M-CAT framework: extended 2D hexagonal honeycomb sheets with c-axis stacking; isolated as one-dimensional nanorods. | 1 · Introduction/Results |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| Ni-CAT nanorod lithium-ion battery anode electroderesearch_0478__mat__ni_cat | Electrode · Target Sample · Composite | Working electrode prepared by mixing Ni-CAT active material, carbon black and CMC at 7:2:1; assembled into 2032 half cells in Ar glovebox.mass loading of ~1 mg cm-2 | 2 · Experimental section |
| As-synthesised Ni-CAT nanorodsresearch_0478__mat__ni_cat | Powder · Target Sample · Pristine Framework | Hydrothermally prepared Ni-CAT nanorods washed with DI water and acetone. | 1 · Results · Fig. 1 |