Synthesis · Construction of 1D conductive Ni-MOF nanorods with fast Li+ kinetic diffusion and stable high-rate capacities as an anode for lithium ion batteries

2 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Partial recipeSource: SI

Route 1: Other

2 · Experimental section

Metal precursorsNi-CAT nanorod active material

Linker precursorsnot_applicable

Solventsnot specified for slurry preparation

Additivescarbon black; carboxymethylcellulose sodium (CMC)

AtmosphereAr glovebox for half-cell fabrication

Work-upMixed active material, carbon black and CMC at 7:2:1; assembled 2032-type coin cells with mass loading ~1 mg cm-2.

Activationnot reported

Scalability contextStandard coin-cell electrode fabrication; current collector, electrolyte, separator and drying details are not specified in the supplied SI text.

Show 3 structured reagent records

Role	Reagent	Amount / concentration	Source
Other	Ni-CAT active material	7 parts by mass	2 · Experimental section
Additive	carbon black	2 parts by mass	2 · Experimental section
Additive	carboxymethylcellulose sodium (CMC)	1 part by mass	2 · Experimental section

Complete recipeSource: SI

Route 2: Hydrothermal

2 · Experimental section - Materials Synthesis

Metal precursors30 mg nickel acetate monohydrate (Sinopharm Chemical Reagent Co., Ltd.)

Linker precursors21 mg 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP, 95 wt.%, J&K)

Solvents12 mL de-ionised water; source wording says 'a solvent mixture of de-ionized (DI) water'

Atmospherenot specified

Temperature85

Time12

Work-upUltra-sonicated for 30 min before heating; washed with sufficient DI water and acetone after heating.

Activationnot reported

Scalability contextSmall-batch solution synthesis using milligram-scale reagents; no scale-up data reported.

Show 3 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	nickel acetate monohydrate	30 mg	2 · Experimental section - Materials Synthesis
Linker	2,3,6,7,10,11-heahydroxytriphenylene (HHTP) (95 wt.%, J&K)	21 mg	2 · Experimental section - Materials Synthesis
Solvent	de-ionized (DI) water	12 mL	2 · Experimental section - Materials Synthesis