Electrochemistry Application — Contorted hexabenzocoronene-based two-dimensional conductive metal-organic framework enabled electrochemical platform for monitoring of rutin in pharmaceuticals and biological samples

3 measurement groups · 7 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Cu3(HBC)2/SPE · Electrode

Cu3(HBC)2/SPE in 0.1 M PBS (pH 3.0), 0 to +1.0 V, scan rate 100 mV/s unless otherwise specified.

Geometry: three-electrode screen-printed electrode with PDMS chamber
Context: composite electrode
Measurement source: 3 · 3.2. Electrochemical properties of Cu3(HBC)2/SPE · Fig. 2B

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Cu3(HBC)2/SPE oxidation peak	0.49 V	—	—	Text Exact Reported	3 · 3.2. Electrochemical properties · Fig. 2B
Cu3(HBC)2/SPE reduction peak	-0.39 V	—	—	Text Exact Reported	3 · 3.2. Electrochemical properties · Fig. 2B
redox-active HBC ligand oxidation peak	-0.13 V	—	—	Text Exact Reported	3 · 3.2. Electrochemical properties · Fig. 2B
redox-active HBC ligand reduction peak	-0.74 V	—	—	Text Exact Reported	3 · 3.2. Electrochemical properties · Fig. 2B

Cu3(HBC)2/SPE · Electrode

Effective surface area from Fe(CN)6(3-/4-) redox response; D = 6.8e-6 cm2/s; c = 5.0 mM.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
effective surface area of bare SPE	0.024 cm2	—	—	Text Exact Reported	4 · 3.2. Electrochemical properties
effective surface area at 0.5 mg/mL Cu3(HBC)2Marked as a best value within this paper	0.0478 cm2	—	—	Text Exact Reported	4 · 3.2. Electrochemical properties

Cu3(HBC)2/SPE · Electrode

5 mM K3[Fe(CN)6]/K4[Fe(CN)6] with 0.1 M KCl; 5 mV amplitude; 0.1 Hz to 1000 kHz.

Geometry: SPE Nyquist plot comparison
Context: composite target compared with bare SPE control
Measurement source: 4 · 3.2. Electrochemical properties of Cu3(HBC)2/SPE · Fig. 2D

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
EIS impedance reduction versus bare SPE	Cu3(HBC)2/SPE impedance roughly half that of bare SPE	—	—	Text Qualitative	4 · 3.2. Electrochemical properties · Fig. 2D